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[en] The energy of the metal-metal-bond of complexes of the type [Me2X8]x- (Me = Re, Mo, Te; X = Cl, Br) has been evaluated in the frame of a simple free electron model and compared with experimental data. Due to the analysis of the bonding orbitals quadruple or stronger Me-Me-bonds have been found, corresponding to σ2π4delta2 and σ2π4delta3 bonding configurations. The charge density distribution of the bonding orbitals has been drawn. (author)
Journal
Wissenschaftliche Zeitschrift der Friedrich-Schiller-Universitaet, Jena. Naturwissenschaftliche Reihe; ISSN 0043-6836; 
; v. 31(6); p. 943-948
; v. 31(6); p. 943-948