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AbstractAbstract
[en] We have made direct absorption measurements of the transition probability and collision broadening of the 1.3-μm 2P/sub 1/2/ → 2P/sub 3/2/ transition of atomic iodine. Atomic iodine was generated in heated iodine vapor, and the spectrum was obtained with a Fourier-transform spectrometer. A transition probability was measured that corresponds to a 2P/sub 1/2/ radiative lifetime of 125 msec. Broadening coefficients of 1.4, 1.7, 3.1, and 1.3 MHz/Torr at 1000 K were found for argon, oxygen, molecular iodine, and atomic iodine, respectively. The intensity of the (2, 4) forbidden electric-quadrupole line was measured and yielded the ratio of electric-quadrupole to magnetic dipole transition probability of 2.7 x 10-3. Molecular absorption spectra of IO and SiI were seen in high-temperature spectra of a quartz cell containing and I2/O2 mixture
Primary Subject
Record Type
Journal Article
Journal
Journal of the Optical Society of America; ISSN 0030-3941; ; v. 73(11); p. 1585-1589
Country of publication
ABSORPTION SPECTROSCOPY, ARGON, ATOM-ATOM COLLISIONS, ATOM-MOLECULE COLLISIONS, ATTENUATION, E2-TRANSITIONS, FORBIDDEN TRANSITIONS, FOURIER TRANSFORMATION, INFRARED RADIATION, INFRARED SPECTROMETERS, IODINE, IODINE OXIDES, LASER RADIATION, LINE BROADENING, M1-TRANSITIONS, MAGNETIC DIPOLES, OXYGEN, QUADRUPOLES, SILICON IODIDES
ATOM COLLISIONS, CHALCOGENIDES, COLLISIONS, DIPOLES, ELECTROMAGNETIC RADIATION, ELEMENTS, ENERGY-LEVEL TRANSITIONS, HALIDES, HALOGEN COMPOUNDS, HALOGENS, INTEGRAL TRANSFORMATIONS, IODIDES, IODINE COMPOUNDS, MEASURING INSTRUMENTS, MOLECULE COLLISIONS, MULTIPOLE TRANSITIONS, MULTIPOLES, NONMETALS, OXIDES, OXYGEN COMPOUNDS, RADIATIONS, RARE GASES, SILICON COMPOUNDS, SPECTROMETERS, SPECTROSCOPY, TRANSFORMATIONS
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