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AbstractAbstract
[en] The solubilities of crystalline Am(OH)3 and AmOHCO3 were measured at 250C in aqueous solutions of 0.1 M NaClO4 by determination of the solution concentrations of Am. Prior to use in the measurements, the solid materials were characterized by their x-ray powder diffraction patterns. The solubility product quotients were calculated from the experimental data. The hydrolysis quotients of Am3+ were also estimated from the hydroxide solubility data. Using the thermodynamic data derived from these experiments and the recently reported formation constants for the Am3+ carbonate complexes, the solid phases and concentrations of solution species of americium in several aqueous carbonate systems were calculated using the computer code MINEQL. 20 references, 1 figure, 1 table
Secondary Subject
Source
Nov 1983; 10 p; Materials Research Society annual meeting; Boston, MA (USA); 14-17 Nov 1983; CONF-831174--51; Available from NTIS, PC A02/MF A01 as DE84004882
Record Type
Report
Literature Type
Conference; Numerical Data
Report Number
Country of publication
ACTINIDE COMPOUNDS, ALKALI METAL COMPOUNDS, AMERICIUM COMPOUNDS, CARBON COMPOUNDS, CARBONATES, CHEMICAL REACTIONS, CHLORINE COMPOUNDS, DATA, DECOMPOSITION, HALOGEN COMPOUNDS, HYDROGEN COMPOUNDS, HYDROXIDES, INFORMATION, NUMERICAL DATA, ORGANIC COMPOUNDS, OXYGEN COMPOUNDS, PERCHLORATES, SODIUM COMPOUNDS, SOLVOLYSIS, TRANSPLUTONIUM COMPOUNDS, TRANSURANIUM COMPOUNDS
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