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AbstractAbstract
[en] High Tc superconductivity has been observed both resistively and magnetically in the new U(Th)-Y-Ba-Cu-O systems. The zero resistance temperature of the three samples with nominal composition of U0.1 Y1.1 Ba0.8 Cu O4-z, U0.15 Y1.05 Ba0.8 Cu4-z and Th0.3 Y0.8 Ba0.8 Cu4-z is 87K, 79K and 74K, respectively. The result of ac magnetic susceptibility measurement implies that the superconducting state is realized in the U-doped samples below 90K. The stoichimetry of the U-Y-Ba-CuO superconductors has the aid of Rutherford backscattering and nuclear reaction 16O(d, p)17O. The analytical results show that the 'real composition' of somples may be different from that of the nomial composition. The X ray diffraction analysis of the U-Y-Ba-Cu-O system shows that none of the peaks can be fitted to the uranium oxides and the other raw materiale structure, and its pattern may be attributed to new multiple phases with structure different from the known singlephase superconducting oxides
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ACTINIDE COMPOUNDS, ALKALINE EARTH METAL COMPOUNDS, BARIUM COMPOUNDS, CHALCOGENIDES, COHERENT SCATTERING, COPPER COMPOUNDS, DIFFRACTION, ELASTIC SCATTERING, ELECTRIC CONDUCTIVITY, ELECTRICAL PROPERTIES, MAGNETIC PROPERTIES, NUCLEAR REACTIONS, OXIDES, OXYGEN COMPOUNDS, PHYSICAL PROPERTIES, RARE EARTH COMPOUNDS, SCATTERING, THERMODYNAMIC PROPERTIES, THORIUM COMPOUNDS, TRANSITION ELEMENT COMPOUNDS, URANIUM COMPOUNDS, YTTERBIUM COMPOUNDS
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