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Andersen, L.H.; Brink, C.; Haugen, H.K.; Hvelplund, P.; Lindhard, J.; Lorents, D.C.; Ruoff, R.; Yu, D.H.
Institute of Physics and Astronomy. Aarhus University1993
Institute of Physics and Astronomy. Aarhus University1993
AbstractAbstract
[en] The discovery of the exceptional stability of C60 (Buckminsterfullerene) and its ions has prompted a large number of experimental and theoretical investigations concerning this soccerball-shaped molecule. After the discovery of a method, by which macroscopic quantities of C60 are available, this molecule has become an obvious candidate for structural and dynamic investigations by atomic-collision experiments. In our experiments, the fragment distributions suggest a mechanism where fragmentation occurs by sequential loss of 'pairs' of carbon atoms. We have continued the C+60 fragmentation studies and also included negative and multiply charged as well as other fullerene ions besides C60. In the case of positive fullerenes, only even-numbered molecules were observed, but for the negative fullerenes, also odd-numbered molecules were recorded on the ∼ 0.5% level relative to the even-numbered components. This finding indicates that the electron structure also plays an important role for the stability of fullerene ions, or perhaps that negative molecules can exist in some isomeric form. The total destruction cross sections for fullerene ions have been measured in several target gases. We are planning to continue with collisional studies of various fullerene ions with special emphasis on a better understanding of the collisionally induced fragmentation for ions in well prepared states, and also endohedral complexes and fusion will be investigated in collision studies. (EG) (8 refs.)
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Knudsen, H.; Grandjean, A. (eds.); Aarhus Univ. (Denmark). Inst. for Fysik og Astronomi; 165 p; 1993; p. 10-15; Available on loan from Risoe Libary, P.O. Box 49, DK-4000 Roskilde, Denmark
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Progress Report
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