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Huntelaar, M.E.; Cordfunke, E.H.P.; Vlaanderen, P. van; Ijdo, D.J.W.
Netherlands Energy Research Foundation (ECN), Petten (Netherlands)1993
Netherlands Energy Research Foundation (ECN), Petten (Netherlands)1993
AbstractAbstract
[en] Strontium zirconium disilicate, SrZrSi2O7, Mr=347.011, monoclinic, P21/c, T=295 K, a=7.7617(9), b=8.0713(10), c=10.0559(11) A, β=111.90(1) , V=584.51(7) A3, Z=4, Dx=3.935(1) Mg.m-3, Dexp=3.928(22) Mg.m-3 (T=294.85 K). Rietveld refinement using neutron powder diffraction data [λ=2.5717(3) A, F(000)=252.45 fm, μR=0.11, 295 contributing reflections] resulted in Rwp=2.72%. The structure can be described by alternately stacking layers containing the ZrO6 octahedra and layers formed by the Si2O7 groups, parallel to (001). Elongated cages are formed for Sr with distorted SrO8 dodecahedrons. The Si2O7 groups are in a nearly eclipsed configuration. The title compound is isostructural with the high temperature form of NaFeP2O7. (orig.)
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Jan 1993; 16 p
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