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AbstractAbstract
[en] Ab initio CI adiabatic potentials and dipole moment matrix elements for the triatomic dication NH22+ in the collinear, asymmetric arrangement have been calculated. A diabatic description of the collision process is obtained by a unitary transformation in a representation that diagonalizes the dipole moment matrix. Neglecting H2 orientation and rotation, cross sections for the charge transfer process N2+ + H2(v=0) → N+ + H2+(v') are determined with a close-coupled quantal method. Results will be compared to recent measurements
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27. annual meeting of the Division of Atomic, Molecular and Optical Physics (DAMOP) of the American Physical Society (APS); Ann Arbor, MI (United States); 15-18 May 1996; CONF-9605105--
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Journal Article
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