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Ebert, W.L.; Bakel, A.J.; Bowers, D.L.; Buck, E.C.; Emery, J.W.
Argonne National Lab., IL (United States). Funding organisation: USDOE Assistant Secretary for Human Resources and Administration, Washington, DC (United States)1997
Argonne National Lab., IL (United States). Funding organisation: USDOE Assistant Secretary for Human Resources and Administration, Washington, DC (United States)1997
AbstractAbstract
[en] A glass that has been tested to understand the corrosion behavior of waste glasses with high soda contents for immobilizing Hanford incidental wastes has been made by melting crushed glass with either TcO2 or NaTcO4 at 1,100--1,300 C. Incorporation of technetium in the glass was affected by solubility or kinetic effects. Metallic technetium inclusions formed in all the TcO2-doped glasses. Inclusions also formed in glasses with added NaTcO4 that were melted at 1,100 C, but a glass melted at 1,200 C did not contain detectable inclusions. The presence of Tc-bearing inclusions complicates the interpretation of results from dissolution tests because of the simultaneous release of technetium from more than one phase, the unknown surface areas of each phase, and the possible incorporation of technetium that is released from one phase into another phase. A glass containing about 0.15 mass % Tc dissolved in the glass is being used in dissolution tests to study the release behavior of technetium
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1997; 11 p; 99. annual meeting of the American Ceramic Society; Cincinnati, OH (United States); 4-7 May 1997; CONF-970568--; CONTRACT W-31109-ENG-38; Also available from OSTI as DE97053352; NTIS; US Govt. Printing Office Dep
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Report
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Conference
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ALKALI METAL COMPOUNDS, CHALCOGENIDES, CHEMICAL REACTIONS, ELEMENTS, MANAGEMENT, MATERIALS, METALS, NATIONAL ORGANIZATIONS, OXIDES, OXYGEN COMPOUNDS, RADIOACTIVE MATERIALS, RADIOACTIVE WASTES, TECHNETIUM COMPOUNDS, TRANSITION ELEMENT COMPOUNDS, TRANSITION ELEMENTS, US DOE, US ORGANIZATIONS, WASTE MANAGEMENT, WASTE PROCESSING, WASTES
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