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Suryanarayanan, R.; Das, A.; Zelenay, I.
Advances in superconductivity: new materials, critical currents and devices1997
Advances in superconductivity: new materials, critical currents and devices1997
AbstractAbstract
[en] Soon after the discovery of superconductivity at 92K in YBa2Cu3O7, it was shown that Pr suppressed superconductivity in Y1-xPrxBa2Cu3O7 when the concentration of Pr exceeded a critical value Xc of 0.55. Further, the value of Xc depended on the ionic radius of the rare earth (at the Y site), Xc being as low as 0.3 for Nd. Several models have been proposed to account for these data but without much success. In the first part we will review the experimental data obtained since 1987. In the second part of this paper, recent results obtained in the last year on the effect of isovalent Sr substitution at the Ba site on xc will be presented. In particular, it was shown that Xc could be increased from 0.3 to 0.45 when 50% of Ba was substituted by Sr in Nd1-xPrxBa2Cu3O7. Further, heating the samples in argon prior to oxygen annealing increased the Tc by 6 to 15K depending on x. In addition, annealing in high pressure oxygen induced superconductivity in certain insulating samples. The normal state properties including Seebeck coefficient will be reported. Neutron diffraction studies indicated a relative slow variation of apical oxygen distance as a function of x(Pr) in Sr substituted systems. In the third part these data will be discussed in the light of certain theoretical models invoking the effect of Prf-CuO2 hybridisation. Our data show that Sr retards this hybridisation and in addition stress the important role played by oxygen reordering along the chains in the Pr substituted Ln123 compounds. (author)
Source
Pinto, R.; Malik, S.K.; Grover, A.K.; Ayyub, P. (Tata Institute of Fundamental Research, Mumbai (India)) (eds.); 419 p; ISBN 81-224-1125-8; ; 1997; p. 25-30; ASMCCD '96: international symposium on advances in superconductivity: new materials, critical currents and devices; Mumbai (India); 17-20 Sep 1996; 36 refs., 5 figs.
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Book
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Conference
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ALKALINE EARTH METAL COMPOUNDS, BARIUM COMPOUNDS, CHALCOGENIDES, COHERENT SCATTERING, COPPER COMPOUNDS, CRYSTAL LATTICES, CRYSTAL STRUCTURE, CRYSTALS, DIFFRACTION, DOCUMENT TYPES, ELEMENTS, HEAT TREATMENTS, NONMETALS, OXIDES, OXYGEN COMPOUNDS, PHYSICAL PROPERTIES, PRASEODYMIUM COMPOUNDS, RARE EARTH COMPOUNDS, SCATTERING, SUPERCONDUCTORS, THERMODYNAMIC PROPERTIES, TRANSITION ELEMENT COMPOUNDS, YTTRIUM COMPOUNDS
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