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Kravchenko, E.A.; Kargin, Yu.F.; Orlov, V.G.; Okuda, T.; Yamada, K., E-mail: ekravch@ionchran.rinet.ru2001
AbstractAbstract
[en] The results of the 209Bi NQR experiments carried out on α-Bi2O3, Bi3O4Br, Bi2M4O9 (M=Al, Ga), Bi2Ge3O9, and Bi4Ge3O12 showed that these compounds are not diamagnets in the conventional sense. The Zeeman perturbed zero-field 209Bi NQR spectra gave an indication that local ordered magnetic fields of the order of 30-200 G exist in these substances comprising neither transition nor rare earth elements. Further aspects of this principally new phenomenon of yet unknown nature were studied by the 209Bi NQR experiments on the Bi4Ge3O12 single crystal in external magnetic fields below 500 Oe, applied at various orientations with respect to the crystal axes. The spectral patterns of dramatically increased intensity and multiplicity, caused by the unknown magnetism of the compound, were observed in applied fields and modeled. Based on the results of the modeling, the conclusions were made that at least four magnetically non-equivalent Bi sites characterized by antiferromagnetically ordered local fields of the order of 30 G are present in the Bi4Ge3O12 crystal; the intensity increase was interpreted to arise from the change in orientation of the electric field gradient axes at the Bi site upon applying an external magnetic field
Source
S0304885300013500; Copyright (c) 2001 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
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