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AbstractAbstract
[en] An analysis on mass transfer losses, or concentration overpotentials in fuel cells is provided. A simplified theory, as proposed in some texts, is derived. This is followed by a more rigorous theoretical foundation of mass transfer, for which the concentration overpotential is obtained as a function of driving force. The solution for the driving force is provided, for the well-known one-dimensional convection-diffusion problem. The methodology is illustrated using the simple example of a solid oxide fuel cell. It is shown that for reduction of O2 at the cathode, the simplified theory is only applicable for very dilute mixtures. At the anode, where H2 is consumed and H2O produced, the simplified theory fails. A linearised theory, appropriate for low mass flow rates is also presented. (author)
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Canadian Hydrogen Association, Toronto, Ontario (Canada); Fuel Cells Canada, Vancouver, British Columbia (Canada); 446 Megabytes; 2003; p. 1-10; Hydrogen and fuel cells conference and trade show; Vancouver, British Columbia (Canada); 8-11 Jun 2003; Available from Canadian Hydrogen Association, Toronto, Ontario (Canada); 11 refs., 10 figs.
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Miscellaneous
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Conference
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