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AbstractAbstract
[en] High-resolution Cl 2p-1 photoelectron (PES) and Cl 2p-1→3pπ-2 normal Auger electron spectra (AES) have been measured using different photon energies. The PES and AES have been fitted simultaneously taking vibrational and electronic lifetime-interference terms into account. Detailed results are presented for the Cl 2p-1→3pπ-2 normal Auger transitions. The equilibrium distances, vibrational energies, and anharmonicities for the 1Σ+, 1Δ, and 3Σ- final states are derived from the intensity distribution of the vibrational substates. The relative intensities for the different Cl 2p-1→3pπ-2 normal Auger transitions are also given. In addition to the Cl 2p-1→3pπ-2 transitions, some fine structures are observed that show a photon energy dependence. These structures are assigned to decays of doubly excited or shake-up/off states
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(c) 2002 The American Physical Society; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
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