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AbstractAbstract
[en] The structure of the Y-phase in the Mg-Ni-Sn system with Mg74.5Ni14.5Sn11 composition was solved by applying the direct methods refined by a standard least square procedure. The space group is N deg. 101 (P42 cm) and the magnitude of the cell parameters are a=b=9.851(2) A and c=6.868(2) A. The final reliability factor is R=0.04 for 1575 independent reflections. The structure can be described in terms of an ideal structure containing two chains of cubes of Mg aligned along the c-direction. In each chain, Sn (resp. Ni) atoms occupy different opposite faces for adjacent cubes forming a stacking of tetrahedra along the c-direction. An alternative description in terms of two distorted polyhedral units is also given and the structure is compared with related inter-metallic compounds
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S0925838803010557; Copyright (c) 2003 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
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