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AbstractAbstract
[en] We discuss how measurements of x-ray circular intensity differentials (XCIDs) could be used to probe the Voigt-Fedorov vector part of optical activity (OA) due to electric dipole-electric quadrupole (E 1E 2) interferences. The first experiment was carried out on a single crystal of zincite (hexagonal ZnO: class 6mm). XCID spectra were recorded in the x-ray resonant diffraction regime near the Zn K edge using the (300) reflection at Bragg angles near 45 deg. In the x-ray range, the effective operator responsible for the vector part of OA can be assigned to the vector product LxΩL-ΩLxL∝n, in which L and ΩL are time-reversal odd operators associated with the orbital angular momentum and the orbital anapole respectively, whereas n is a true time-reversal even electric dipole. This is consistent with the pyroelectric properties of zincite crystals
Source
S0953-8984(07)41365-0; Country of input: International Atomic Energy Agency (IAEA)
Record Type
Journal Article
Journal
Country of publication
ANGULAR MOMENTUM, CHALCOGENIDES, COHERENT SCATTERING, CRYSTAL LATTICES, CRYSTAL STRUCTURE, CRYSTALS, DIFFRACTION, DIPOLES, ELECTROMAGNETIC RADIATION, IONIZING RADIATIONS, MULTIPOLES, OPTICAL PROPERTIES, OXIDES, OXYGEN COMPOUNDS, PHYSICAL PROPERTIES, RADIATIONS, REFLECTION, SCATTERING, SPECTRA, ZINC COMPOUNDS
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