Filters
Results 1 - 1 of 1
Results 1 - 1 of 1.
Search took: 0.029 seconds
Ogita, N.; Kojima, R.; Takasu, Y.; Hasegawa, T.; Kondo, T.; Udagawa, M.; Takeda, N.; Ikeno, T.; Ishikawa, K.; Sugawara, H.; Kikuchi, D.; Sato, H.; Sekine, C.; Shirotani, I., E-mail: nogita@hiroshima-u.ac.jp2007
AbstractAbstract
[en] Raman scattering of skutterudite compounds RT4X12 (R=La, Ce, Pr, Nd, Sm and Yb, T=Fe, Ru and Os, X=P and Sb) have been measured. All first-order Raman active phonons are observed and are assigned as the pnictogen vibrations. At the low energy region, the second-order phonons, including the vibration of the rare-earth ions with a flat phonon dispersion, are observed in the spectra of SmRu4P12 and ROs4Sb12. The second-order phonons can be observed for the sample with the larger cage space. The large displacement in the large cage space and the large density of state due to the flat phonon dispersion increase the intensity of the second-order Raman scattering process. The intensity of the second-order phonon are also affected by the valence of the rare-earth ions
Primary Subject
Source
17. international conference on magnetism; Kyoto (Japan); 20-25 Aug 2006; S0304-8853(06)01344-8; Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Record Type
Journal Article
Literature Type
Conference
Journal
Country of publication
Reference NumberReference Number
INIS VolumeINIS Volume
INIS IssueINIS Issue