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[en] In this work, it has been found that the 6p valence band of the recently discovered icosahedral [Pb12]2- shell forms a perfect partner for the 5f shell of an enclosed actinide atom such as plutonium. Detailed DFT calculations suggest that the system is viable. It could, on good grounds, be characterized as a 32e system. Experimental results are described into details. (O.M.)
Journal
Angewandte Chemie (International Edition); ISSN 1433-7851; 
; v. 46(no.9); p. 1427-1430
; v. 46(no.9); p. 1427-1430