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[en] The published data on the synthesis of organomagnesium compounds assisted by metal complex catalysts are generalised and described systematically for the first time. Hydro-, carbo- and cyclomagnesiation reactions of unsaturated compounds with R1MgR2 (R1 = Alk, Ar; R2 = H, Hal; R1 = R2 = Alk) catalysed by Ti, Zr and other transition metal salts and complexes are considered. Selected examples of applications of organomagnesium reagents to organic synthesis are given.
Journal
Russian Chemical Reviews (Print); ISSN 0036-021X; 
; v. 74(9); p. 807-823
; v. 74(9); p. 807-823