[en] Picosecond time-resolved Laser pump/X-ray probe experiments are becoming general and powerful tools to explore structural dynamics in materials and biological sciences. In order to perform time-resolved experiments, we constructed the beam line NW14A at the Photon Factory Advanced Ring, KEK. This beam line is designed to conduct a wide variety of time-resolved X-ray measurements, such as time-resolved X-ray diffraction, scattering, spectroscopy and imaging. Experimental protocols for time-resolved fluorescence XAFS and X-ray solution scattering measurements are presented. (author)