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AbstractAbstract
[en] Zirconium treated graphite tubes were investigated and compared with non-treated and palladium coated ones for in situ trapping of selenium hydride generated in a flow injection system. Selenium was effectively trapped on zirconium treated tubes at trapping temperatures of 300-600C, similar to those observed for palladium, whereas trapping temperatures higher than 600C had to be used with non-treated tubes. Zirconium treated tubes used in this work showed good stability up to 300 trapping/atomization cycles, with precision better than 5%, characteristic masses of 42 (peak height) and 133 pg (peak area) of selenium were obtained. Sensitivity of zirconium and palladium treatments were similar, but zirconium offered the advantage of a single application per tube. Detection limits were 0.11 (peak height) and 0.23 ng (peak area) for a 1 ml sample volume. (Copyright (c) 1999 Elsevier Science B.V., Amsterdam. All rights reserved.)
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Country of input: International Atomic Energy Agency (IAEA); This record replaces 31061935
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Journal Article
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Spectrochimica Acta. Part B, Atomic Spectroscopy; ISSN 0584-8547; ; CODEN SAASBH; v. 54(2); p. 343-353
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