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[en] Gamma irradiation route has been explored for reduction of aqueous vanadium solutions. In situ generated 2-hydroxy-2-propyl radical has been evaluated for reduction of aqueous V(V). The process was studied for a monoprotic acid media, mixture of mono and polyprotic acid media and only polyprotic acid media. Precipitation of V(IV) occurred in the monoprotic acid media while the reduction to soluble lower oxidation state vanadium species could be obtained in both polyprotic media. (author)
Source
Board of Research in Nuclear Sciences, Department of Atomic Energy, Mumbai (India); Indian Society for Radiation and Photochemical Sciences, Radiation and Photochemistry Division, Bhabha Atomic Research Centre, Mumbai (India); 294 p; ISBN 81-88513-61-X; 
; 2014; p. 92-93; TSRP-2014: 12. DAE-BRNS biennial Trombay symposium on radiation and photochemistry; Mumbai (India); 6-9 Jan 2014; 2 figs.
; 2014; p. 92-93; TSRP-2014: 12. DAE-BRNS biennial Trombay symposium on radiation and photochemistry; Mumbai (India); 6-9 Jan 2014; 2 figs.