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El Mendili, Y.; Bardeau, J.-F.; Greneche, J.-M.; Randrianantoandro, N.; Grasset, F.; Cador, O.; Guizouarn, T., E-mail: nirina@univ-lemans.fr2014
AbstractAbstract
[en] Structural and magnetic properties of γ-Fe2O3 nanoparticles of 4 nm diameter, dispersed into silica SiO2 matrix with a wide range value of volume fraction (0.05 to 1), were investigated. Produced γ-Fe2O3@SiO2 nanocomposites consist of an assembly of very small single domain magnetic object (<10 nm) with a random distribution of both inter-particle distance and direction of particle magnetic moment. We focused on the determination of a magnetic percolation threshold, defined as the magnetic particles concentration value above which the magnetic properties of isolated particles vanished in favor of a magnetic collective behavior induced by magnetic interactions. A percolation threshold value of 0.63 was obtained by a local probe technique such as 57Fe Mössbauer spectrometry and confirmed by global magnetic measurements through zero-field cooled, field-cooled, and ac susceptibility data. Below this threshold, dynamic ac magnetization measurements show a thermally activated Arrhenius dependence of the blocking temperature of superparamagnetic nanoparticles and above this critical value, one observes a slowing down of their dynamic properties, which lead toward the establishment of a spin-glass like state
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(c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
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CHALCOGENIDES, EVEN-ODD NUCLEI, FERRIMAGNETIC MATERIALS, INTERMEDIATE MASS NUCLEI, IRON COMPOUNDS, IRON ISOTOPES, ISOTOPES, MAGNETIC MATERIALS, MAGNETISM, MATERIALS, MINERALS, NUCLEI, OXIDE MINERALS, OXIDES, OXYGEN COMPOUNDS, PARTICLES, PHYSICAL PROPERTIES, SILICON COMPOUNDS, STABLE ISOTOPES, TRANSITION ELEMENT COMPOUNDS
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