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AbstractAbstract
[en] In order to catalyse the oxidation of tritium gas safely, two new hydrophobic catalysts were prepared for the emergency disposal of tritium gas leakage by choosing two inorganic hydrophobic substances as carrier and Pt as active component. Under room temperature, the catalysed oxidation ratio of 3‰ (V/V) -1% (V/V) hydrogen gas in air is higher than 95%, the speed constant is higher than 2.0 s"-"1; under room temperature, conversion ratio of 0.3‰ hydrogen in air is higher than 90%, the speed constant is higher than 1.6 s"-"1. It can be concluded that the catalysts can be used to catalyse tritium waste gas oxidation. Furthermore, Pt- inorganic hydrophobic catalysts has obviously better Ⅱ catalysing ability than Pt-PTFE and lower ability than Pt-SDB in H_2-HTO isotopic exchange, because the pressure resistance of Pt-Ⅱ is much higher than Pt-SDB, it can be used to the CECE cell of heavy water detritium system. (authors)
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China Chemical Society, Beijing (China); 126 p; Aug 2008; p. 11; 26. annual academic conference of China Chemical Society--modern nuclear chemistry and radiochemistry; Tianjin (China); 13-16 Jul 2008; Available from China Nuclear Information Centre (China Institute of Nuclear Information & Economics), inisservice_cn@163.com
Record Type
Miscellaneous
Literature Type
Conference
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BETA DECAY RADIOISOTOPES, BETA-MINUS DECAY RADIOISOTOPES, CHALCOGENIDES, CHEMICAL REACTIONS, DEUTERIUM COMPOUNDS, DIMENSIONLESS NUMBERS, ELEMENTS, FLUIDS, FLUORINATED ALIPHATIC HYDROCARBONS, GASES, HALOGENATED ALIPHATIC HYDROCARBONS, HYDROGEN COMPOUNDS, HYDROGEN ISOTOPES, ISOTOPES, LIGHT NUCLEI, MATERIALS, NONMETALS, NUCLEI, ODD-EVEN NUCLEI, ORGANIC COMPOUNDS, ORGANIC FLUORINE COMPOUNDS, ORGANIC HALOGEN COMPOUNDS, ORGANIC POLYMERS, OXIDES, OXYGEN COMPOUNDS, PETROCHEMICALS, PETROLEUM PRODUCTS, PLASTICS, POLYETHYLENES, POLYMERS, POLYOLEFINS, POLYTETRAFLUOROETHYLENE, RADIOACTIVE MATERIALS, RADIOISOTOPES, SYNTHETIC MATERIALS, TEMPERATURE RANGE, TRITIUM COMPOUNDS, WASTES, WATER, YEARS LIVING RADIOISOTOPES
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