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Brachet, J.C.; Le Saux, M.; Lezaud-Chaillioux, V.; Dumerval, M.; Houmaire, Q.; Lomello, F.; Schuster, F.; Monsifrot, E.; Bischoff, J.; Pouillier, E.
TOP FUEL 2016 Proceedings2016
TOP FUEL 2016 Proceedings2016
AbstractAbstract
[en] For enhanced accident tolerant fuels for light water reactors application, chromium coatings on zirconium based nuclear fuel claddings are developed and studied at CEA in the framework of the French CEA-EDF-AREVA collaborative program. The results obtained so far, mainly on Zircaloy-4 substrate, show very good corrosion resistance in nominal conditions and significant enhancement of the resistance of the material to oxidation in steam at high temperature (HT), up to 1300 Celsius degrees, with a drastic decrease of hydrogen release and/or pick-up. The present paper reports some new results obtained on chromium coated Zircaloy-4 claddings tested in loss-of-coolant accident (LOCA) conditions. In order to investigate the potential effect of the coating on the cladding mechanical behavior at HT and the capacity of the coating to sustain significant substrate deformation (i.e., during ballooning until burst occurrence) without generalized cracking/peeling, a preliminary limited set of internal pressure creep and temperature ramp tests have been performed in steam environment thanks to the EDGAR facility. The thermal-mechanical tests were done for testing/burst temperatures ranging from 600 C. degrees (αZr phase domain) up to 1000 C. degrees (βZr phase domain) on 50 cm long low-tin Zircaloy-4 cladding samples with a 15 μm thick outer chromium coating. It is shown that: -) whatever the applied temperature/pressure values, the chromium coating is still fully adherent after having experienced ballooning and burst, including at the vicinity of the burst opening where the Zircaloy-4 clad substrate is highly deformed; -) a HT strengthening effect of the coating on the overall creep clad behavior is evidenced when compared to uncoated Zircaloy-4 cladding materials tested in the same conditions; -) as a consequence, it is observed that, in the 600-750 C. degrees temperature range (αZr phase domain) and after burst occurrence, the balloon sizes (i.e., 'uniform' and maximum hoop strains) are generally reduced when compared to uncoated materials; -) regarding the burst mechanism in the βZr phase temperature range (1000 C. degrees), it is interesting to observe that, even if some ballooning occurred prior to the cladding failure, the actual burst openings are generally very small (in the order of 1 mm2 or less), reducing the risk of fuel fragments dispersal in the coolant
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American Nuclear Society - ANS, 555 North Kensington Avenue, La Grange Park, IL 60526 (United States); 1670 p; ISBN 978-0-89448-734-7; ; 2016; p. 1173-1178; TOP FUEL 2016: LWR fuels fuels with enhanced safety and performance; Boise, ID (United States); 11-15 Sep 2016; Available from: American Nuclear Society - ANS, 555 North Kensington Avenue, La Grange Park, IL 60526 (US), also available in CD-Rom; Country of input: France; 8 refs.
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Book
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Conference
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ACCIDENT-TOLERANT NUCLEAR FUELS, CHROMIUM, CLADDING, COATINGS, COMPARATIVE EVALUATIONS, CORROSION RESISTANCE, CRACKING, CREEP, HYDROGEN, LOSS OF COOLANT, MECHANICAL TESTS, OXIDATION, SUBSTRATES, TEMPERATURE RANGE 0400-1000 K, TEMPERATURE RANGE 1000-4000 K, TIN, WATER COOLED REACTORS, WATER MODERATED REACTORS, ZIRCALOY 4
ACCIDENTS, ALLOYS, ALLOY-ZR98SN-4, CHEMICAL REACTIONS, CHROMIUM ADDITIONS, CHROMIUM ALLOYS, CORROSION RESISTANT ALLOYS, DECOMPOSITION, DEPOSITION, ELEMENTS, ENERGY SOURCES, EVALUATION, FUELS, HEAT RESISTANT MATERIALS, HEAT RESISTING ALLOYS, IRON ADDITIONS, IRON ALLOYS, MATERIALS, MATERIALS TESTING, MECHANICAL PROPERTIES, METALS, NONMETALS, NUCLEAR FUELS, PYROLYSIS, REACTOR ACCIDENTS, REACTOR MATERIALS, REACTORS, SURFACE COATING, TEMPERATURE RANGE, TESTING, THERMOCHEMICAL PROCESSES, TIN ALLOYS, TRANSITION ELEMENT ALLOYS, TRANSITION ELEMENTS, ZIRCALOY, ZIRCONIUM ALLOYS, ZIRCONIUM BASE ALLOYS
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