[en] The effect of Organo-Chlorine Compounds (OCC) on the radiation structuring of SKN-40 was investigated in filled model systems with 5 mass. h. of ZnO.The content of gel was determined at various dosages of OCC after irradiation with doses from 5 to 40 MRad. With increasing dosages of OCC, it takes part in the formation of rubber. After radiation exposure, the optimal conditions for the content of gel systems are 62-65%, and the activity in the processes of radiation structuring of OCC is located in the same row that was composed of the composition of the heating. The effective concentration of cross-links at optimal dosages of OCC (n'_e 10''-''1''9, cm''-''3) in the optimum vulcanization constitute model systems with HCCP-5,3, adduct 1-5,3, adduct 2-6,3, adduct 3-6,5. In the presence of OCC, the optimal dose of radiation is reduced, so they can be considered as sensitizers of radiation structuring. Thus, it was found that the investigated OCC are effective structuring agents for SKN-40 both during heating and exposure to λ irradiation.