[en] The combustion wave propagation in Al–CuO and Al–Bi₂O₃ termite mixtures was experimentally investigated. Waveforms of electric current through the reaction area between electrodes with a given potential difference, chronograms of piezo- and photodiode response, the data of pyrometric measurements, as well as photos of the glowing area were obtained and analyzed. There were revealed the advance filtration of the gas component through pores of mixture, the generation of charges providing considerable electrical conductivity of chemical reaction products, the connection of electrical conductivity dynamics with the optical radiation of the chemical conversion region. (paper)