[en] Highlights: • Dinuclear lanthanide complexes bridged by 2,3,5,6-tetra(2-pyridyl)pyrazine. • X-ray crystal structure and Hirshfield surfaces. • Solid-state luminescence and DFT calculations. Six dinuclear lanthanide(III) nitrato complexes [Ln(NO₃)₃(H₂O)]₂(μ-tppz) (where tppz = 2,3,5,6-tetra(2-pyridyl) pyrazine and Ln(III) = Nd (1), Sm (2), Eu (3), Gd (4), Tb (5), and Dy (6)) with bis-tridentate N-heterocyclic 2,3,5,6-tetra(2-pyridyl)pyrazine as bridging ligand have been solvothermally synthesized and characterized via elemental analysis, infrared spectroscopy, thermogravimetric analysis, single-crystal X-ray diffraction, and powder X-ray diffraction. The 3-D Hirshfeld surface and 2-D fingerprint plots show that the main interactions in 1–6 are the O⋯H/H⋯O intermolecular interactions with relative contributions of about 62%. Although the poor lanthanide(III)-centered luminescence properties clearly point to the efficiency of nonradiative quenching processes (presence of water molecules in the coordination sphere of the lanthanide(III) ions), the ligand tppz is better suited to sensitize the lanthanide(III)'s emissions of Eu^III and Nd^III than Sm^III, Tb^III, and Dy^III. Finally, the magnetic data of Dy^III comple×6 reveals antiferromagnetic coupling between Dy^III ions.