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AbstractAbstract
[en] The activity of deposited nickel catalysts was studied in benzaldehyde hydration dependina on the nature of other metal additions and the nature of carrier. Al2O3, TiO2, SiO2, ZrO2 and their mixtures were used as carriers. Dependence o Ni/ZrO2 catalyst activity on the quantity of incorporated metal additions is demonstrated. Introduction of 10% Cr or Al into Ni/ZrO2 increases benzaldehyde hydration rate by 5.5 and 4.2 correspondingly. Simultaneously the decrease of potential displacement value on 40-50 mv is taking place which indicates the strengthening of hydrogen bond with the surface of a mixed nickel catalyst. Value of the apparent activation energy of benzaldehyde hydration is in the 5-9 cal/mol range. It was found that application of carriers and additions facilitating the strengthening of hydrogen bond with the surface of nickel catalyst, leads to obtaining of highly active nickel contacts for benzaldehyde hydration
Original Title
Issledovanie nanesennykh nikelevykh katalizatorov pri gidrirovanii benzal'degida
Primary Subject
Source
For English translation see the journal J. Gen. Chem. USSR.
Record Type
Journal Article
Journal
Zhurnal Obshchej Khimii; v. 45(11); p. 2516-2519
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