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AbstractAbstract
[en] It was recently shown that the calcination at 1000 C in Ar of a gel formed from the reaction of uranyl nitrate and citric acid yields nanometric UO2 clusters, completely embedded and well-dispersed in a carbon matrix. Uranium carbide powders with high sinterability are then easily obtained from the carbothermal reduction of such precursor by a further heat treatment in vacuum at temperatures of 1200-1600 C for few minutes. Here we report the first results of our investigation on the possibility to obtain the nitride form from the same precursor, by conducting the last step in a nitrogen-containing atmosphere, and on the granulation of such powders by a novel electro-dropping method. The work is being performed within the EU-funded FREDMANS Project. (authors)
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CEA, IRESNE, Direction des Energies (France); Joint Research Centre of the European Commission - JRC, Bruxelles (Belgium); Romanian Institute for Nuclear Research - RATEN, Arges County (Romania); 71 p; 2023; p. 19; Nufuel 2023: Research into nuclear fuel in Europe; Marseille (France); 7-9 Nov 2023; 2 refs.; Available from the INIS Liaison Officer for France, see the INIS website for current contact and E-mail addresses
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