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Forte Giacobone, A F; Burkart, A L; Pizarro, R; Rodriguez S; Belloni, M; Croatto, F; Ferrari, F; Herrera, C; Mendizabal, M; Montes, J; Rodriguez Aliciardi, M; Saucedo, R; Ovando, L
XXXIX Annual meeting of the Argentine Association of Nuclear Technology (AATN 2012)2012
XXXIX Annual meeting of the Argentine Association of Nuclear Technology (AATN 2012)2012
AbstractAbstract
[en] In order to improve water quality, and mitigate recurrent bio corrosion phenomena affecting the components of the Process Water System of the CNE, a combined water treatment adding a commercial biocide product, based on bromide, to the currently injected chlorine was proposed. The aim of this study was to evaluate the effect of the added biocide on the kinetics of biofilm formation and growth, which is the precursor process to microbiological corrosion, and on the corrosion rates of carbon steel of pipes, heat exchanger shells and other system devices. For this purpose, a test bench was designed and built, reproducing the flow conditions at certain parts of the system. This facility was installed in the filtration shed of the Water Plant of the CNE. The test bench consisted of two parallel chambers, I and II, each in turn divided into a section for determining biofilm growth and corrosion rates of carbon steel coupons and another one to measure the kinetics of biofilm growth on stainless steel coupons. Both chambers received lake water chlorinated for 15 minutes each day. The chamber II received also the biocide. The corrosion rate in carbon steel coupons was evaluated by weight loss and Linear Polarization Resistance (LPR) measurements. The kinetics of biofilm growth on carbon steel coupons was measured using disruptive methods followed by quantification of the protein and carbohydrate content as an estimation of total biomase. The following bacterial groups were quantified through the dilution-extinction method: total aerobic bacteria, acid-producing bacteria, total anaerobic bacteria, sulfate reducing bacteria and bacteria precipitating iron and manganese. On the stainless steel coupons, the percent of coverage was evaluated by epi fluorescence microscopy. The corrosion rate results obtained both by weight loss as by LPR, showed no significant differences between both chambers, with and without biocide. Regarding the kinetics of biofilm growth on carbon steel coupons, no significant differences between chambers were found. The analysis of the percentage of coverage on stainless steel coupons matches the results for carbon steel coupons. It was concluded that, under the current operating conditions, it is unlikely that the addition of a complementary biocide that acts by interaction with chlorine, could produce a beneficial effect of reduction and control of the biological material present in the water of the Process Water System of the CNE. It has been suggested to evaluate the possibility of revising the current chlorination scheme and improving its efficiency before implementing any complementary biocide addition scheme (author)
Original Title
Evaluacion de la eficacia del agregado de un biocida para el control de la corrosion microbiologica en canerias y equipos del sistema de agua de procesos de la central nuclear Embalse (CNE)
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Asociacion Argentina de Tecnologia Nuclear (Argentina); [vp.]; 2012; 9 p; AATN 2012: 39. Annual meeting of the Argentine Association of Nuclear Technology; AATN 2012: 39. Reunion anual de la Asociacion Argentina de Tecnologia Nuclear; Buenos Aires (Argentina); 3-7 Dec 2012; Country of input: Chile; 2 refs., 4 figs., 2 tabs
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