[en] We model the effects of the atomic thermal motion on the propagation of a light pulse in an electromagnetically induced transparency medium by introducing a set of effectively temperature-dependent parameters, including the Rabi frequency of the coupling field, optical density and relaxation rate of the ground state coherence, into the governing equations. The validity of this effective theory is verified by the close agreement between the theoretical results and the experimental data.

[en] We present a numerical scheme to study the dynamics of slow light and light storage in an electromagnetically-induced-transparency (EIT) medium at finite temperatures. Allowing for the motional coupling, we derive a set of coupled Schroedinger equations describing a boosted closed three-level EIT system according to the principle of Galilean relativity. The dynamics of a uniformly moving EIT medium can thus be determined by numerically integrating the coupled Schroedinger equations for atoms plus one ancillary Maxwell-Schroedinger equation for the probe pulse. The central idea of this work rests on the assumption that the loss of ground-state coherence at finite temperatures can be ascribed to the incoherent superposition of density matrices representing the EIT systems with various velocities. Close agreements are demonstrated in comparing the numerical results with the experimental data for both slow light and light storage. In particular, the distinct characters featuring the decay of ground-state coherence can be well verified for slow light and light storage. This warrants that the current scheme can be applied to determine the decaying profile of the ground-state coherence as well as the temperature of the EIT medium.

[en] Three mixed-alkali metals uranyl silicates, Na_3K_3[(UO_2)_3(Si_2O_7)_2]·2H_2O (1), Na_3Rb_3[(UO_2)_3(Si_2O_7)_2] (2), and Na_6Rb_4[(UO_2)_4Si_1_2O_3_3] (3), have been synthesized by high-temperature, high-pressure hydrothermal reactions at 550 °C and 1440 bar, and characterized by single-crystal X-ray diffraction, photoluminescence, and thermogravimetric analysis. Compound 1 and 2 are isostructural and contain layers of uranyl disilicate. The smaller cation, Na"+, is located in the intralayer channels, whereas the larger cations, K"+ and Rb"+, and water molecule are located in the interlayer region. The absence of lattice water in 2 can be understood according to the valence-matching principle. The structure is related to that of a previously reported mixed-valence uranium(V,VI) silicate. Compound 3 adopts a 3D framework structure and contains a unique unbranched dreier fourfold silicate chain with the structural formula {uB,4"1_∞}["3Si_1_2O_3_3] formed of Q"2, Q"3, and Q"4 Si. The connectivity of the Si atoms in the Si_1_2O_3_3"1"8"− anion can be interpreted on the basis of Zintl–Klemm concept. Crystal data for compound 1: triclinic, P-1, a=5.7981(2) Å, b=7.5875(3) Å, c=12.8068(5) Å, α=103.593(2)°, β=102.879(2)°, γ=90.064(2)°, V=533.00(3) Å"3, Z=1, R1=0.0278; compound 2: triclinic, P-1, a=5.7993(3) Å, b=7.5745(3) Å, c=12.9369(6) Å, α=78.265(2)°, β=79.137(2)°, γ=89.936(2)°, V=546.02(4) Å"3, Z=1, R1=0.0287; compound 3: monoclinic, C2/m, a=23.748(1) Å, b=7.3301(3) Å, c=15.2556(7) Å, β=129.116(2)°, V=2060.4(2) Å"3, Z=2, R1=0.0304. - Graphical abstract: Three mixed-alkali metals uranyl silicates were synthesized under hydrothermal conditions at 550 °C and 1400 bar and structurally characterized by single-crystal X-ray diffraction. Two of them have a layer structure with the alkali metal cations within and between the layers. The third one adopts a 3D framework structure and contains a unique unbranched dreier fourfold silicate chain formed of Q"2, Q"3, and Q"4 Si. - Highlights: • Three new mixed-alkali metals uranyl silicates were synthesized by high-T, high-P hydrothermal method and structurally. • Two compounds adopt a layer structure and the third one has a 3D framework structure. • The 3D framework structure contains a unique unbranched dreier fourfold silicate chain formed of Q"2, Q"3, and Q"4 Si.

[en] The efficiency of a nonlinear optical process is proportional to the interaction time. We report a scheme of all-optical switching based on two motionless light pulses via the effect of electromagnetically induced transparency. One pulse was stopped as the stationary light pulse (SLP) and the other was stopped as stored light. The time of their interaction via the medium can be prolonged and, hence, the optical nonlinearity is greatly enhanced. Using a large optical density (OD) of 190, we achieved a very long interaction time of 6.9 μs. This can be analogous to the scheme of trapping light pulses by an optical cavity with a Q factor of 8×10⁹. With the approach of using moving light pulses in the best situation, a switch can only be activated at 2 photons per atomic absorption cross section. With the approach of employing a SLP and a stored light pulse, a switch at only 0.56 photons was achieved and the efficiency is significantly improved. Moreover, the simulation results are in good agreement with the experimental data and show that the efficiency can be further improved by increasing the OD of the medium. Our work advances the technology in quantum information manipulation utilizing photons