AbstractAbstract
[en] Electron spin resonance spectra of free radicals formed in the radiolysis of benzene-2,1-diazoquinone-4-sulphonic acid in polycrystalline form were recorded. Two different radical species were found: the first one was stable at 77 K, whereas the second one was formed at higher temperatures. The thermal stability of the latter was investigated in the 20-100 deg C temperature range, and the kinetic parameters for the decomposition process were determined. An appropriate mechanism of radiolysis was proposed. (author)
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10 refs.
Record Type
Journal Article
Journal
Journal of Radioanalytical and Nuclear Chemistry; ISSN 0236-5731; ; CODEN JRNCD; v. 117(2); p. 81-90
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AROMATICS, BETA DECAY RADIOISOTOPES, BETA-MINUS DECAY RADIOISOTOPES, CHEMICAL RADIATION EFFECTS, CHEMICAL REACTIONS, COBALT ISOTOPES, CRYSTALS, DECOMPOSITION, INTERMEDIATE MASS NUCLEI, ISOMERIC TRANSITION ISOTOPES, ISOTOPES, KINETICS, MAGNETIC RESONANCE, MINUTES LIVING RADIOISOTOPES, NUCLEI, ODD-ODD NUCLEI, ORGANIC ACIDS, ORGANIC COMPOUNDS, ORGANIC NITROGEN COMPOUNDS, ORGANIC OXYGEN COMPOUNDS, ORGANIC SULFUR COMPOUNDS, QUINONES, RADIATION EFFECTS, RADIOISOTOPES, RESONANCE, YEARS LIVING RADIOISOTOPES
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AbstractAbstract
[en] Electron spin resonance spectra have been used to gain information on the mechanism of radiolysis of aqueous solutions of methylene blue. The identity and behaviour of the semiquinone radicals formed as intermediate reduction products were discussed for strongly acid and for alcaline solutions. In order to obtain information on the radiolytic mechanism in strongly acidic media, irradiation was performed in the presence of various types of scavengers: sodium formate, glucose, succinic acid, hydroquinone and D,L-α alanine. (author)
Source
11 refs.
Record Type
Journal Article
Journal
Radiochemical and Radioanalytical Letters; ISSN 0079-9483; ; v. 57(1); p. 9-22
Country of publication
ALANINES, ALDEHYDES, ALKALI METAL COMPOUNDS, AMINES, AMINO ACIDS, AROMATICS, AZINES, CARBOHYDRATES, CARBOXYLIC ACID SALTS, CARBOXYLIC ACIDS, CHEMICAL RADIATION EFFECTS, CHEMICAL REACTIONS, CHLORIDES, CHLORINE COMPOUNDS, DECOMPOSITION, DICARBOXYLIC ACIDS, DISPERSIONS, DRUGS, ELECTROMAGNETIC RADIATION, HALIDES, HALOGEN COMPOUNDS, HETEROCYCLIC COMPOUNDS, HEXOSES, HOMOGENEOUS MIXTURES, IONIZING RADIATIONS, KINETICS, MAGNETIC RESONANCE, MIXTURES, MONOSACCHARIDES, ORGANIC ACIDS, ORGANIC COMPOUNDS, ORGANIC NITROGEN COMPOUNDS, ORGANIC OXYGEN COMPOUNDS, ORGANIC SULFUR COMPOUNDS, PHENOTHIAZINES, RADIATION EFFECTS, RADIATIONS, REACTION KINETICS, RESONANCE, SACCHARIDES, SOLUTIONS
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Clime, L.; Beron, F.; Ciureanu, P.; Ciureanu, M.; Cochrane, R.W.; Yelon, A., E-mail: liviu.clime@polymtl.ca2006
AbstractAbstract
[en] We present a phenomenological model for the interaction field in ferromagnetic nanowire arrays and use it to obtain the effective anisotropy field of individual nanowires, from the in-plane saturation field of the array. In contrast to other methods which may be used to estimate this parameter, the proposed strategy requires no knowledge of the saturation magnetization nor of the nanowire radius. Applied to three arrays of different compositions, this approach yields an equivalent anisotropy field of the individual nanowires approximately equal to Ms/2, indicating that its origin is the demagnetizing field of the wire
Primary Subject
Source
S0304-8853(05)00534-2; Copyright (c) 2005 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
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