[en] The mission of the Materials Fabrication Division (MFD) is to provide fabrication services and technology in support of all programs at Lawrence Livermore National Laboratory (LLNL). MFD involvement is called for when fabrication activity requires levels of expertise, technology, equipment, process development, hazardous processes, security, or scheduling that is typically not commercially available. Customers are encouraged to utilize private industry for fabrication activity requiring routine processing or for production applications. Our waste minimization (WM) program has been directed at source reduction and recycling in concert with the working definition of waste minimization used by EPA. The principal focus of WM activities has been on hazardous wastes as defined by RCRA, however, all pollutant emissions into air, water and land are being considered as part of the program. The incentives include: (1) economics, (2) regulatory conformance, (3) public image and (4) environmental concern. This report discusses the waste minimization program at LLNL

[en] Lawrence Livermore National Laboratory (LLNL) and Technic, Inc. have entered into a CRADA (Cooperative Research and Development Agreement) with the goal of providing industry with an environmentally benign alternative to the presently used silver cyanide plating process. This project has been in place for about six months and results are quite promising. The main objective, that of deposition of deposits as thick as 125 um (5 mils), has been met. Property data such as stress and hardness have been obtained and the structure of the deposit has been analyzed via metallography and x-ray diffraction. These results will be presented in this paper, along with plans for future work

No abstract available

No abstract available

No abstract available

[en] Uranium--0.75 percent Ti alloy is considerably easier to etch and plate than U--2.3 percent Nb alloy. According to humidity tests, both alloys are corrosion resistant when plated with 25 to 50 μm thick Ni coatings. The 0.75 percent Ti alloy is pretreated by etching in FeCl₃, NiCl₂/HNO₃ or ZnCl₂/HNO₃ solutions; the 2.3 percent Nb alloy is etched in CuCl₂ solution. By machining a specific taper on a part, cleaning and activating the surfaces, mating the parts, and building up an electroplated triangular segment between the tapered edges, the 0.75 percent Ti alloy can be joined to steel (4340) and Al (2024 and 7075). Tensile tests showed failure to occur in the parent metals, rather than in the plated joint section

[en] Procedures were developed and utilized whereby 105-mm U-Ti penetrators were plated with 1.0 mil of nickel and 0.2 mil of zinc and then chromated. Twenty-three full-size penetrators were coated to demonstrate the feasibility of the system and to provide parts for ballistic tests. Dimensional inspection of the parts before and after etching and plating revealed the coating process to be viable and repeatable

[en] As part of a program for the US Army directed at improving the corrosion performance of U-0.75 Ti, specimens were coated with Zn-10 Ni alloy electroplate and then subjected to various corrosion tests. This work revealed that the Zn-Ni coatings provided good protection for U-0.75 Ti in salt fog and in non-sealed moist-nitrogen systems. In sealed, moist-nitrogen environments the Zn-Ni coatings deteriorated quickly and provided no protection. Some plating with Zn alone, using some of the new non-cyanide plating solutions, was also attempted, but the results were inconsistent

[en] Results of quantitative adhesion tests indicate that an acid etch followed by a dilute zincate treatment should be used when plating on beryllium. Applications wherein beryllium was joined to itself or to stainless steel are presented. (U.S.)

[en] Quantitative adhesion data are presented for a variety of electroplated stainless steel type alloys. Results show that excellent adhesion can be obtained by using a Wood's nickel strike or a sulfamate nickel strike prior to final plating. Specimens plated after Wood's nickel striking failed in the deposit rather than at the interface between the substrate and the coating. Flyer plate quantitative tests showed that use of anodic treatment in sulfuric acid prior to Wood's nickel striking even further improved adhesion. In contrast activation of stainless steels by immersion or cathodic treatment in hydrochloric acid resulted in very reduced bond strengths with failure always occurring at the interface between the coating and substrate