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AbstractAbstract
[en] At the present time, several technologies have been proposed to remove dyes from water, adsorption is one of the most feasible methods and adsorbents with different properties, such as activated carbon, zeolites, clays and hydrogels among others. In this work, the sorption behavior of blue 1 dye by a natural clay from a site located in the Center-East of Mexico, and other modified with iron chloride were determined. The materials were characterized by X-ray diffraction to analyze its crystal structure, by scanning electron microscopy and elemental microanalysis of energy dispersive X-ray spectrometry to determine the composition and morphology, and the zero point charges were also determined to know the charge distribution on the surface of the clay. The ph effect, contact time, dye concentration and temperature were the parameters considered in this study. The results showed that clay does not suffer any important changes in its structure after the chemical treatments (modification with ferric chloride and contact with blue 1 solutions). The ph influences lightly the adsorption of the dye with natural clay, but the same effect is not observed in the ferric modified clay among the factor ph 6 and 8. The equilibrium time and the sorption capacity for natural clay were 48 hours and 6.16 mg/g, while for the ferric clay were 24 hours and 14.22 mg/g. Adsorption kinetics results were best adjusted to the pseudo first and pseudo second order models. Adsorption isotherms were best adjusted to the Langmuir model, indicating that both clays have a homogeneous surface. Thermodynamic parameters (E, ΔS and ΔG and ΔH) were calculated for the dye adsorption by the natural clay using data of the adsorption kinetics at temperatures between 20 and 50 C, indicating that the adsorption process is exothermic. For the case of ferric clay, it was not possible to calculate these thermodynamic parameters because the adsorption capacities were similar in the range of selected temperatures. (Author)
Original Title
Remocion de colorante azul 1 de soluciones acuosas con una arcilla modificada con cloruro de hierro
Primary Subject
Source
2012; 111 p; Thesis (chem. eng.)
Record Type
Miscellaneous
Literature Type
Thesis/Dissertation
Report Number
Country of publication
ADSORPTION, ADSORPTION ISOTHERMS, AQUEOUS SOLUTIONS, CHARGE DISTRIBUTION, CLAYS, CONCENTRATION RATIO, CRYSTAL STRUCTURE, DYES, IRON CHLORIDES, KINETICS, MEXICO, MICROANALYSIS, PH VALUE, POINT CHARGE, SCANNING ELECTRON MICROSCOPY, SURFACES, WATER REMOVAL, X-RAY DIFFRACTION, X-RAY SPECTROSCOPY, ZEOLITES
CHLORIDES, CHLORINE COMPOUNDS, COHERENT SCATTERING, DEVELOPING COUNTRIES, DIFFRACTION, DIMENSIONLESS NUMBERS, DISPERSIONS, ELECTRIC CHARGES, ELECTRON MICROSCOPY, HALIDES, HALOGEN COMPOUNDS, HOMOGENEOUS MIXTURES, INORGANIC ION EXCHANGERS, IODIDES, IODINE COMPOUNDS, ION EXCHANGE MATERIALS, IRON COMPOUNDS, IRON HALIDES, IRON IODIDES, ISOTHERMS, LATIN AMERICA, MATERIALS, MICROSCOPY, MINERALS, MIXTURES, NORTH AMERICA, REMOVAL, SCATTERING, SILICATE MINERALS, SOLUTIONS, SORPTION, SPECTROSCOPY, TRANSITION ELEMENT COMPOUNDS
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