[en] Recent seismic events have underlined the risks nuclear dry storage casks (DSCs) are exposed. Dominion Virginia Power's North Ann during Virginia 5.8 earthquake, August 2011: - 25 of 27 DSCs moved on their concrete pad; - DSCs shifted from 1.0 to 4 1/2 inches; - Metal components were not damaged; - No radiation was released. The main goals of this study is to evaluate the long-term seismic performance of DSCs using experimental tests. Through use of Scaled DSC Specimens on the UNR six Degree-of-Freedom (DOF) Shaking Table. Scaled model specimen shall satisfy the following: - Model aspect ratio shall cover the range in the available commercial DSCs; - Scaled 1/2.5 specimens shall be presentative for the actual prototype (specially under vertical excitation); - Designed specimen shall sustain handling, sliding and impact during testing. Selected evaluation basis earthquakes: - Near Field Earthquake (M6.0 at 2 km); - Far Field Earthquake (M8.0 at 20 km). The level of spectral acceleration using NUREG 6728 seismic hazard curves. Developed for the following return periods: - 1,000-year return period; - 30,000-year return period. Design: - Design handling system for overpack and MPC; - Check stresses on the outer cylindrical shell of the overpack in case of using anchorage system for the DSCs; - Check resulted stresses due to impact of the scaled specimen on the supporting concrete pad; - Check safety of shell thicknesses; - Design of connections between different parts; - Design of the concrete pads to resist impact during the test. Future Plans: - Evaluate the long-term seismic performance of the existing dry storage casks in U.S. and develop guidelines for re-licensing operating periods of DSCs. - Provide a performance based design guidelines for DSCs to maintain its safety against earthquakes

[en] Dry Storage Casks (DSCs) store spent nuclear fuel (SNF), usually at sites contiguous to nuclear power plants known as Independent Spent Fuel Storage Installation (ISFSI). DSCs have been considered as a temporary storage solution, and are usually licensed for 20 years, which can be extended up to an operating periods of 60 years. Recently, however, DSCs have been considered as a potential mid-term solution for hundreds of years. This consideration requires reevaluation of DSC performance under a larger seismic hazard. That leads to larger horizontal and vertical accelerations. This study is a part of a research project evaluating the seismic response of free-standing DSCs under long return period seismic events. This article assess whether the response of free-standing structures under seismic excitation is repeatable. For this purpose, experimental tests were conducted using a six degree-of-freedom (6DOF) shake table. During the experimental tests, several ground motions were repeated multiple times to obtain the dynamic response under identical loading conditions. Scaled casks of four aspect ratios (radius to centroidal height ratio, r/h_cg) were studied: 0.39, 0.43, 0.55 and 0.62. The specimens studied are considered to be 1:2.5 and 1:3.5 scaled model of generic prototype casks. The experimental results show that a small change in initial conditions leads to change in the boundary condition of moving bodies and in combination with acceleration being applied at different frequencies contained within the applied ground motions may lead to a large variation in the response. (authors)

[en] Highlights: • The probability of pinching failure does not exceed 0.2%. • Only highly embrittled cladding fails. • Radial hydride embrittlement controls hydride-related embrittlement. • The diametric cladding deformations are small. - Abstract: A probabilistic methodology to investigate pinching failure of pressurized water reactor (PWR) spent nuclear fuel (SNF) rod cladding is presented. The considered accident scenario is a 9-m SNF transportation cask drop after long-term SNF dry storage. The offset strain was used to evaluate cladding failure. A set of 3000 pinching scenarios was generated via Latin Hypercube Sampling (LHS) of geometrical, material, and loading parameters and finite element (FE) models were developed to simulate each scenario. The methodology considers hydride-related cladding embrittlement related to SNF dry storage cool-down. Regression and interpolation models were developed to estimate the cladding offset strain capacity as a function of cladding hydrogen content, peak vacuum drying cladding hoop stress, and cladding temperature at the moment of load application. The probabilistic results indicate a small likelihood of hydride-related pinching failure in the considered accident scenario, after 30 or 300 years of SNF dry storage.

[en] Polyaniline nanoparticles (PANI-Nps) have been used in several applications; however, there are few publications related to the use in the photothermal therapy. PANI-Nps have high optical absorbance in the near-infrared region and in this wavelength range, biological systems are relatively transparent. For this reason, these materials can be used to absorb energy and to generate heat that destroys cancer cells selectively. PANI-Nps with average size of ca. 200 nm and neutral zeta potential were synthesized and characterized by DLS, SEM, and zeta potential. The kinetics of incorporation of PANI-Nps into LM2 cell line was monitored using UV–Vis spectrophotometry. The analysis of cell viability after PANI-Nps exposure shows that these nanoparticles are not cytotoxic even at high concentration and show no change in cell morphology and metabolic activity. Furthermore, we found that nanoparticle cell uptake reaches the maximum value c.a. 3 h after incubation. Cells were targeted by Pani-Nps and irradiated, resulting in significant elevation of intracellular ROS and heat production. One of the mechanisms of PANI-Nps-mediated photothermal killing of cancer cells apparently involved oxidative stress resulting in apoptotic cell death.

[en] Highlights: • Strain capacity reduces by one order of magnitude due to hydrogen charging. • Radial hydride treatment at 80 MPa does not cause significant radial hydrides. • Loading capacity reduces by about 20–30% due to hydrogen charging. • Fuel pellet support increases loading capacity by several orders of magnitude.