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Sharma, Poonam; Dhawan, Anil; Jayraj, J.; Kamachi Mudali, U., E-mail: anildhawan11@yahoo.com
Proceedings of the international corrosion prevention symposium for research scholars: souvenir2013
Proceedings of the international corrosion prevention symposium for research scholars: souvenir2013
AbstractAbstract
[en] The potentiodynamic polarization studies were carried out on Zr based bulk amorphous alloy Zr57Cu15.4Ni12.6Al10Nb5 and Zr59Cu20Ni8Al10Ti3 in solutions of 1 M, 6 M and 11.5 M HNO3 aqueous media at room temperature. As received specimens of Zr57Cu15.4Ni12.6Al10Nb5 (5 mm diameter rod) and Zr59Cu20Ni8Al10Ti3 (3 mm diameter rod) were polished with SiC paper before testing them for potentiodynamic polarization studies. The amorphous nature of the specimens was checked by X-ray diffraction. The bulk amorphous alloy Zr59Cu20Ni8Al10Ti3 shows the better corrosion resistance than Zr57Cu15.4Ni12.6Al10Nb5 alloy in the aqueous HNO3 media as the value of the corrosion current density (Icorr) for Zr57Cu15.4Ni12.6Al10Nb5 alloy were found to be more than Zr59Cu20Ni8Al10Ti3 alloy in aqueous HNO3 media. The improved corrosion resistance of Zr59Cu20Ni8Al10Ti3 alloy is possibly due to the presence of Ti and formation of TiO2 during anodic oxidation. Both Zr based bulk amorphous alloys shows wider passive range at lower concentration of nitric acid and the passive region gets narrowed down with the increase in concentration. A comparison of data obtained from both the Zr-based bulk amorphous alloys is made and results are discussed in the paper. (author)
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Gateway India Section, NACE International, Mumbai (India); [118 p.]; 2013; p. PP3; CORSYM-2013: international corrosion prevention symposium for research scholars; Chennai (India); 28 Feb - 2 Mar 2013
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