AbstractAbstract
[en] Aminoacyl derivatives of 3-phenoxychromone have been synthesized. Electron paramagnetic resonance spectra of title compound have been recorded. The chemical and physical properties are discussed
Original Title
Khimiya geteroanalogov izoflavonov. 23. Sintez aminoatsil'nykh proizbodnykh 3-fenoksikhromona
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5 refs., 3 tabs., 2 figs.
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Journal Article
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Khimiya Geterotsiklicheskikh Soedinenij; ISSN 0132-6244; ; (no.6); p. 744-748
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AbstractAbstract
[en] Benzodioxane analogs of chalcones and their epoxides have been prepared. Different types of analogs of natural flavonolignan - silibin - have been synthesized from these compounds. The PMR spectra of the new compounds and the results of the preliminary biological testings are reported and discussed
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Translated from Khim. Geterotsikl. Soedin.; 22: No.2, 192-198(Feb 1986).
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Journal Article
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BIOLOGICAL EFFECTS, BORON FLUORIDES, CATALYSIS, CHEMICAL SHIFT, CHLOROFORM, DEUTERATION, DEUTERIUM COMPOUNDS, DIOXANE, ENZYME INHIBITORS, EPOXIDES, EUROPIUM COMPLEXES, FLAVONES, HETEROCYCLIC COMPOUNDS, HYDROGEN PEROXIDE, HYPERFINE STRUCTURE, ISOMERIZATION, MATERIALS TESTING, MOLECULAR STRUCTURE, MULTIPLETS, NMR SPECTRA, SELENIUM OXIDES, SODIUM HYDROXIDES, SYNTHESIS
ALKALI METAL COMPOUNDS, BORON COMPOUNDS, CHALCOGENIDES, CHEMICAL REACTIONS, COMPLEXES, FLAVENOIDS, FLUORIDES, FLUORINE COMPOUNDS, HALIDES, HALOGEN COMPOUNDS, HYDROGEN COMPOUNDS, HYDROXIDES, ORGANIC CHLORINE COMPOUNDS, ORGANIC COMPOUNDS, ORGANIC HALOGEN COMPOUNDS, ORGANIC OXYGEN COMPOUNDS, OXIDES, OXYGEN COMPOUNDS, PEROXIDES, RARE EARTH COMPLEXES, SELENIUM COMPOUNDS, SODIUM COMPOUNDS, SPECTRA, TESTING
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[en] We have studied some peculiarities of the spectral-fluorescent properties of the natural compound - umbelliferone and herniarin - in aprotonic and proton donor solvent of different polarity, Based on quantum chemical analysis performed by the semiempirical AM1 method, when considering changes of the electronic charge and orders of bonds. In the ground and first excited states, we have interpreted the anomalously high Stokes shifts and mirror symmetry of the absorption and fluorescence bands for these compounds in aprotonic solvents. It is established that the fluorescence spectra of umbelliferone in water, ethanol, alkaline and acidic solutions, differ greatly from such spectra for herniarin. This is related to the detachment and transfer of the proton in the neutral form of umbelliferone. upon photoexcitation, which is accompanied by the possible formation of the anion, cation and tautomer, depending on pH of media. A good agreement between the calculated and experimental values of maxima of electronic bands of these forms is achieved. (authors)
Original Title
Ehlektronnoe stroenie i spektral'no-fluorestsentnye svojstva umbelliferona i gerniarina
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16 refs., 2 tabs., 4 figs.
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Journal Article
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