[en] Heat-treatment and machining are two key process when manufacturing pressurizer forging, which need to be performed heat-treatment many times to assure its mechanical strength because of being used as the pressure-resistant vessel. The mechanical property of forging must be satisfied the technology requirements after preliminary heat-treatment and property heat-treatment. Because the enclosure heat of Qinshan phase-II nuclear power project is a special big type spherical surface, it is very difficult to perform its mechanical machining. The author introduces a mechanical machining method to overcome the difficulty for hoisting and determining datum

[en] Biomass carbon dots synthesized by biological waste conform to the trend of ecological environmental protection and the requirements of green chemistry, which show great application potential in practice. In the study, we used watermelon peels as the raw materials to synthesize a novel blue biomass carbon dots (CDs) by a hydrothermal process with high fluorescence quantum yield of 22.8%. Through bulk polymerization and solgel method, two kinds of core–shell nanospheres were developed as fluorescent probes to recognize and detect ethyl carbamate (EC) rapidly without complex samples pretreatment. The obtained CDs@MIPs integrated the high-performance optical characteristics of CDs with excellent selectivity and adsorption of MIPs, which showed ideal linear relationships in the EC concentration range 1–120 μg L⁻¹ and low LOD of 0.57 μg L⁻¹ and 0.94 μg L⁻¹, respectively. Both CDs@MIPs have a short equilibration time which was around 20 min, and the imprinting factors (IF) are 4.04 and 2.62. The recoveries of the six spiked samples were satisfying, and the RSD precisions were lower than 5.57%. Gas chromatography–mass spectrometry was seen as a parallel analysis to validate the correctness of the results, which indicated the practicability and reliability of the developed method. This proposal strategy of optical sensors provided an effective channel for trace EC recognition, with numerous advantages, involving eco-friendly, low cost, high sensitivity, separation effect, and good selectivity. Graphical abstract:

[en] Graphical abstract: -- Highlights: •PPY-GO-BiCoPc composite was formed using a simple electrochemical method for the first time. •A novel PoPD-MIP sensor based on PPY-GO-BiCoPc composite had been fabricated. •The PPY-GO-BiCoPc functional composite was introduced to improve performance of the sensor. •Highly sensitive, selective and stable sensor had been achieved. •The established MIP sensor could be promising in food safety analysis. -- Abstract: A facile and efficient molecularly imprinted polymer (MIP) recognition element of electrochemical sensor was fabricated by directly electro-polymerizing monomer o-phenylenediamine (oPD) in the presence of template quinoxaline-2-carboxylic acid (QCA), based on one-step controllable electrochemical modification of poly(pyrrole)-graphene oxide-binuclear phthalocyanine cobalt (II) sulphonate (PPY-GO-BiCoPc) functional composite on glassy carbon electrode (GCE). The MIP film coated on PPY-GO-BiCoPc functional composite decorated GCE (MIP/PPY-GO-BiCoPc/GCE) was presented for the first time. The synergistic effect and electro-catalytic activity toward QCA redox of PPY-GO-BiCoPc functional composite were discussed using various contrast tests. Also, the effect of experimental variables on the current response such as, electro-polymerization cycles, template/monomer ratio, elution condition for template removal, pH of the supporting electrolyte and accumulation time, were investigated in detail. Under the optimized conditions, the proposed MIP sensor possessed a fast rebinding dynamics and an excellent recognition capacity to QCA, while the anodic current response of square wave voltammetry (SWV) was well-proportional to the concentration of QCA in the range of 1.0 × 10⁻⁸–1.0 × 10⁻⁴ and 1.0 × 10⁻⁴–5.0 × 10⁻⁴ mol L⁻¹ with a low detection limit of 2.1 nmol L⁻¹. The established sensor was applied successfully to determine QCA in commercial pork and chicken muscle samples with acceptable recoveries (91.6–98.2%) and satisfactory precision (1.9–3.5% of SD), demonstrating a promising feature for applying the MIP sensor to the measurement of QCA in real samples

[en] The Xikuangshan (XKS) mine in China has vast quantities of waste material and reported antimony (Sb) and arsenic (As) contamination of water in the mine area. This study estimated the potential of acid mine drainage (AMD) generation by waste material at XKS mine by using paste pH, acid base accounting and net acid generation geochemical static tests. Distribution of Sb and As in surface and groundwater in relation to mine waste AMD producing potential was also investigated. Thirty four (34) water samples and representative samples of three mine wastes from different periods (fresh, 10 and 50 years) were collected for this study: waste rock, smelting slag and tailings. The AMD prediction shows that waste rock (from 10 year period) is acid producing while the fresh mine waste had alkaline paste pH indicating the presence of reactive carbonates. Hence AMD generation may have occurred after a long time due to dissolution of carbonates. Water analysis found Sb with higher concentration than As with means of 3.74 mg/L and 0.19 mg/L respectively. Highest Sb and As concentrations were observed in the North mine along the water flow path from waste heaps and tailing pond; Mine water in the South mine also had elevated Sb and As concentrations. Mining activities at the XKS mine have accelerated Sb and As releases because of the disturbed natural equilibrium. Proper mine waste management and collection and treatment of outflow from the waste rock heaps and tailing ponds seem to be a promising mitigation options. - Highlights: • High levels of Sb and As were detected in alkaline water at Xikuangshan mine. • Static test showed that mine waste aged over 10 years was acid generating. • Mine waste influenced the high concentration of Sb and As in water. • The Sb/As ratios in water favored Sb because of high Sb content in the ore body.

[en] A supersensitive chiroptical-responsive system of enantioselectively recognizing L- and D-tryptophan (Trp) based on ( +)-diacetyl-L-tartaric anhydride-functionalized 1,3,5-triformylphloroglucinol (DTA-functionalized Tp) was constructed for the first time. With a high fluorescence quantum yield of 15.2% and fluorescence lifetime of 57.6 μs, DTA-functionalized Tp as both fluorescent and chiral recognition nanoprobe was used for the discrimination of L- and D-Trp with excitation/emission maxima at 330/490 nm within 3 min. The linear range of the fluorescence sensing was 0.002–0.15 μg mL⁻¹, and the detection limit achieved 1.4 ng mL⁻¹. Furthermore, a smartphone was employed as a detector and processor to couple with the chiroptical-responsive nanoprobe for establishing a novel and visual integration system for rapid and real-time detection of chiral amino acids with a detection limit of 13 ng mL⁻¹. The spiked recoveries of L-Trp in two commercially available functional beverages ranged from 86.00 to 118.33% in fluorescence and smartphone-based sensing system. Based on the excellent chiroptical-responsive effects, high stability, and biocompatibility, the chiroptical-responsive nanoprobe was successfully applied to visual optosensing and fluorescence imaging in response to L- and D-Trp in HeLa cells. This discrimination methodology with high sensitivity and enantioselectively shows great potential for in-site visually monitoring chiral amino acids in real food samples and tracking physiological processes. Graphical abstract:

[en] A novel and facile method was proposed for preparation of red emissive N-doped carbon dots encapsulated within molecularly imprinted polymers (RNCDs@MIPs) using a one-pot room-temperature reverse microemulsion polymerization. RNCDs used citric acid and urea as carbon and nitrogen sources by one-step solvothermal synthesis with the optimum emission of 620 nm. Unique optical properties of RNCDs coupled with high selective MIPs make the RNCDs@MIPs conjugate capable to adsorb specific targets of pyrraline (PRL), such a binding event was then transduced to quench fluorescence response signal of the RNCDs. RNCDs@MIPs for PRL showed linearity from 0.1 to 40 μg/L, with a detection limit of 65 ng/L. The RNCDs@MIPs exhibited a good reproducibility of 4.67% obtained from four times of rebinding for PRL. The optosensing probe was successfully applied to the detection of PRL in fatty foods with the spiked recovery of 85.93–106.96%. Graphical abstract

[en] In order to solve technical issues in the development of vacuum target chamber in Shenguang-Ⅲ laser facility, such as weak lateral stiffness and field precision fabrication and installation, the structural design and the whole manufacture process have been proposed. Combining the global stability design of the target area, the vertical pedestal, and the lateral support structure that can provide passive damping have been designed. The thickness of the chamber shell has been optimized. The alignment precision of the field fabrication of the target chamber is satisfied by using the special fixtures, i. e. the laser tracker, the six dimensional adjustment mechanism, and the custom-machined spacers, for accurately boring holes. The analysis shows that the mean root-mean-square value of displacement of 48 focusing lenses is 2.8 μm. After construction, the height deviation of the target chamber center is ±0.12 mm, the horizontal deviation is ±0.18 mm. The centering deviations of the important flanges are from 0.35 mm to 0.4 mm. (authors)

[en] Quantum-dots-doped covalent organic frameworks in a molecularly imprinted network (QDs-doped COFs@MIP) were developed for detection of nereistoxin (NRT)-related insecticide in tap water. The preparation of QDs-doped COFs@MIP was easy to accomplish via one-pot synthesis at room temperature. QDs-doped COFs@MIP quenched by targeting thiosultap due to the photoinduced charge transfer. A Brunauer–Emmett–Teller surface area of 186.20 m² g⁻¹ and a maximum adsorption capacity of 771 mg g⁻¹ of the QDs-doped COFs@MIP exhibited good selectivity and adsorption capacity. Direct fluorescence determination was established over the range 5–100 μg L⁻¹ (R² = 0.9959) with a detection limit of 1.60 μg L⁻¹. Furthermore, 86.5–106.5% recoveries of spiked tap water were achieved. The determination system was feasible for tracing the NRT-related insecticide with high accuracy and good repeatability and reproducibility.

[en] An efficient and rapid fluorescent nanoprobe is described for the determination of the aroma compound 4-ethylguaiacol (4-EG). A molecularly imprinted polymer was doped with a covalent organic framework (COF) grafted onto carbon nanodots that was prepared by one-pot reverse microemulsion polymerization. Amino groups at the surface of carbon nanodots coordinate to the COFs to produce a strong bond and this warrants thermal and chemical stability of the probe. Remaining free amino groups interact with the phenolic hydroxyl groups of 4-EG through acid–base pairing interactions. The probe, with excitation/emission maxima at 350/440 nm, responds to 4-EG due to the charge transfer to the carbon nanodots. Under optimized conditions, fluorescence drops linearly as the concentrations of 4-EG increase from 0.025 to 1 μg mL⁻¹, with a detection limit of 17 ng mL⁻¹. The probe was applied to the determination of 4-ethylguaiacol in Chinese Baijiu and wine samples after pretreatment by a single dilution step. The recoveries of spiked samples ranged from 78.4to 110.1%.

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[en] A robust multi-dimensional sensing array based on VBimBF₄B/MAA-anchored quantum dot (QD)-grafted covalent organic frameworks (COFs) [(V-M)/QD-grafted COFs] was established via one-pot strategy. The multi-dimensional sensing array has the outstanding advantages of physicochemical and thermal stability, large specific surface area, and regular pore structures. The assistance of ionic liquid VBimBF₄B enhanced the transduction efficiency, and the synergistic effect of COFs enhanced detection efficiency. The improved multi-dimensional sensing array by COFs and ionic liquid VBimBF₄B served to identify seven insecticides by non-specific interactions via hydrogen bonding, and the differences in the kinetics of the binding to the insecticides resulted in variation of the three-output channel (fluorescence, phosphorescence, and light scattering) signals, thus generating a distinct optical fingerprint. The unique fingerprint patterns of seven kinds of common insecticides at 200 μg L⁻¹ were successfully discriminated using principal component analysis and clustered heat map analysis. The multi-dimensional sensing array showed a response to seven insecticides based on three spectral channels over the range of 0.001–0.4 μg mL⁻¹ with a limit of detection of 1.08–18.68 μg L⁻¹. The spiked recovery of tap water was 79.86–134.22%, with RSD ranging from 0.89–14.9%. This study broadens the applications of sensing arrays technology and provides a promising building block for insecticide determination. Graphical abstract: