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Kahl, L.; Ruiz-Lopez, M.C.; Saidl, J.; Dippel, T.
Kernforschungszentrum Karlsruhe G.m.b.H. (Germany, F.R.). Inst. fuer Nukleare Entsorgungstechnik; Kernforschungszentrum Karlsruhe G.m.b.H. (Germany, F.R.). Projekt Wiederaufarbeitung und Abfallbehandlung1982
Kernforschungszentrum Karlsruhe G.m.b.H. (Germany, F.R.). Inst. fuer Nukleare Entsorgungstechnik; Kernforschungszentrum Karlsruhe G.m.b.H. (Germany, F.R.). Projekt Wiederaufarbeitung und Abfallbehandlung1982
AbstractAbstract
[en] In the 'Institut fuer Nuklare Entsorgungstechnik' the borosilicate glass VG 98/12 has been developed for the solidification of the high level radioactive waste (HLW). This borosilicate glass can be used in a direct heated ceramic melter and forms together with the HLW the borosilicate glass product GP 98/12. This borosilicate glass product has been examined in detail both in liquid and solid state. The elements contained in the HLW can be incorporated without problems. Only in a few exceptions the concentration must be kept below certain limits to exclude the formation of a second phase ('yellow phase') by separation. No spontaneous crystallization and no crystallization over a long time could be observed as long as the temperature of the borosilicate glass product is kept below its transformation area. Simulating accidental conditions in the final storage, samples had been leached at temperatures up to 2000C and pressures up to 130 bar with saturated rock salt brine and saturated quinary salt brine. The leaching process seems to be stopped by the formed 'leached layer' on the surface of the borosilicate glass product after a limited leaching time. Detailed investigations have been started to explain this phenomenon. (orig.)
[de]
Im Institut fuer Nukleare Entsorgungstechnik wurde das Borosilikatglas VG 98/12 zur Verfestigung von hochradioaktiven Abfaellen (HAW) entwickelt. Das Borosilikatglas ist in einem direkt beheizten, keramischen Schmelzofen verwendbar und fuehrt mit dem HAW zum Borosilikatglasprodukt GP 98/12. Dieses Borosilikatglasprodukt wurde in fluessigem und festem Zustand untersucht. Die darin enthaltenen Elemente koennen ohne Probleme aufgenommen werden. Nur in wenigen Ausnahmen muss die Konzentration in bestimmten Grenzen gehalten werden, um die Bildung der zweiten ('gelben') Phase auszuschliessen. Solange die Temperatur des Borosilikatglasproduktes unterhalb des Transformationsbereichs gehalten wird, ist keine spontane Kristallisation oder Kristallisation ueber lange Zeit zu beobachten. Bei der Simulation von Stoerfallbedingungen im Endlager wurden Proben bei einer Temperatur von 2000C und einem Druck bis zu 130 bar in gesaettigter Salzloesung und gesaettigter quinaerer Salzlauge ausgelaugt. Der Auslaugprozess wird anscheinend von der gebildeten Auslaugschicht auf der Oberflaeche des Borosilikatglasproduktes nach einer begrenzten Auslaugzeit gestoppt. Detaillierte Untersuchungen wurden begonnen, um dieses Phaenomen zu klaeren. (orig.)Primary Subject
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Apr 1982; 53 p; Also published in German in KFK--3251, February 1982: Herstellung und Charakterisierung eines verbesserten Borosilikatglases zur Verfestigung von hochradioaktiven Spaltproduktloesungen (HAW).
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AbstractAbstract
[en] The aim of the study is to measure the characteristic magnitudes taken into account in the safety analysis of fire risk in laboratories and factories and in the prediction calculation code. It is particularly concerned with the spread of fire, the evolution of thermal flux, the temperature and the heat and pollution flow. The trials comprise thermal decomposition and combustion of semi-finished organic products, for example, constituents of the confinement building, as well as electric cable bundles of varying shapes and sizes. The trial set-up is simple and rapid, and benefits from a systematic approach. The reproducibility of the results gives rise to a differentiation in materials as a function of their behaviour. The experimental procedure consists of placing the sample under conditions simulating an outbreak of fire in an unconfined atmosphere. The test material is submitted to a known, controlled incident thermal flux which, depending on the tests, is delivered by a radiant gas or electric panel. Two types of trial are carried out, depending on whether the minimum thermal flux giving rise to auto-inflammation or the discharge of noxious gases is to be determined. A propane pilot light is used to ignite the combustible gases. The temperature, thermal discharge, mass loss and concentration and flow of gas are recorded continuously. Data entry and treatment are carried out by an acquisition unit connected to a microcomputer. The results obtained lead to a comparison of the fire behaviour of different types of polymer panel (for minimum heat flow of auto-inflammation), and estimate the discharge of chemical and thermal pollution and the mass loss rate for various types and volumes of cable. (author). 3 refs, 8 figs, 2 tabs
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International Atomic Energy Agency, Vienna (Austria); Proceedings series; 581 p; ISBN 92-0-020489-9; ; 1989; p. 461-470; IAEA; Vienna (Austria); International symposium on fire protection and fire fighting in nuclear installations; Vienna (Austria); 27 Feb - 3 Mar 1989; IAEA-SM--305/33
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AbstractAbstract
[en] Electrical, structural and compositional properties of n-ZnO/c-Si heterojunctions prepared by chemical spray pyrolysis on single-crystal n-type and p-type monocrystalline silicon(1 0 0) substrates are examined with the C-V method and admittance spectroscopy at temperature ranges between 223 and 373 K. The n-ZnO/c-Si heterojunctions show a height barrier consistent with the difference in energy of the work functions of Si and ZnO; however, the n-ZnO:Al/c-Si heterojunctions present a more complex behavior due to the defects at or near the n-ZnO:Al/c-Si interface, causing a Fermi energy pinning
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S0921510704001102; Copyright (c) 2004 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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Materials Science and Engineering. B, Solid-State Materials for Advanced Technology; ISSN 0921-5107; ; CODEN MSBTEK; v. 110(1); p. 87-93
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AbstractAbstract
[en] Eight power plants are operating in Spain, 5 of them are PWR, 2 are BWR and one GCR type. All light water spent fuels are stored at pools in each NPP, being built of concrete, designed as seismic class I and stainless steel lined, and the saturation of their capacities is estimated to occur, on average, between 1993 and 2005. The GCR spent fuels are also stored in the NPP pool until its periodic sending to reprocessing. Racks are designed to maintain the spent fuel with a Keff < 0.95. The pool water is cooled, filtered and demineralized. Controls are carried out on water temperature, level in the pool, flow rate in the cooling circuit, radiation level and radioactive concentration in the air, water chemistry, etc. Irradiated fuel assemblies are visually inspected by means of TV cameras and the cooling and purification systems are also visually inspected. A strategy is being elaborated for intermediate storage of spent fuels, considering both wet and dry storage. (author). 2 tabs
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International Atomic Energy Agency, Vienna (Austria); 110 p; May 1988; p. 17-23; Technical committee meeting on spent fuel surveillance and monitoring methods; Vienna (Austria); 27-30 Oct 1987
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AbstractAbstract
[en] For solidification of high-level radioactive fission product solutions (HAW), the borosilicate glass VG 98/12 was developed. In the present article, physical properties (density, thermal expansion, viscosity, electric and thermal conductivity), thermal behaviour, and hydrolytic stability (leaching) of the glass material are reported, the chemical composition with 15 wt.% inactive simulated HAW oxides is presented. (GSCH)
[de]
Fuer die Verfestigung hochradioaktiver Spaltproduktloesungen (HAW) wurde das Borosilikatglass VG 98/12 entwickelt. In dem vorliegenden Artikel wird ueber die physikalischen Eigenschaften (Dichte, Waermeausdehnung, Viskositaet, elektrische und Waermeleitfaehigkeit), ueber das thermische Verhalten und ueber die hydrolitische Bestaendigkeit (Auslaugung) des Glasswerkstoffes berichtet, die chemische Zusammensetzung mit 15 Gew.% inaktiv simulierter HAW Oxide wird mitgeteilt. (GSCH)Original Title
Das Borosilikatglas VG 98/12 zur Verfestigung von hochradioaktiven Spaltproduktloesungen (HAW)
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KFK Nachrichten; ISSN 0340-756X; ; v. 15(1); p. 11-15
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Laborde, J.C.; Pourprix, M.; Lopez, M.C.; Savornin, J.
Proceeding of the 21st DOE/NRC nuclear air cleaning conference. Volume 2, Sessions 9--161991
Proceeding of the 21st DOE/NRC nuclear air cleaning conference. Volume 2, Sessions 9--161991
AbstractAbstract
[en] One of the main roles of ventilation in a nuclear plant is to maintain dynamic containment during normal or accidental operating conditions. Among the incidents likely to affect a nuclear installation, fire is one of those which, coming from the safety standpoint, requires the greatest attention because it is one of the most probable risks. The consequences of a fire have to be analyzed not only in the room where it breaks out, but also for the entire ventilation network. To evaluate these consequences and develop strategies against fire, the Commissariat a l'Energie Atomique uses several test rigs and calculation codes by which the impact of a fire upon the sensitive points of a network can be determined. Research and development studies currently under way give priority to the clogging of High Efficiency Particulate Air filters. Beginning with polymer fires in a 85 m3 ventilated room, the influence of filter clogging on the characteristic parameters of the associated ventilated network is highlighted. The resultant modeling study following these experiments reveals that coupling of a ventilation code with a fire code cannot be disassociated from the development of a filter clogging model. This paper also gives the first experimental results relative to the determination of the variation, according to time and mass of deposited aerosols, of the air flow resistance of a filter clogged by aerosols derived from combustion of standard polymers used in the nuclear industry (methyl acrylate polymer, polyvinyl chloride). A methodology to extend the results obtained on the clogging test rig to any ventilation network is then described
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First, M.W. (ed.) (Harvard Univ., Boston, MA (USA)); Nuclear Regulatory Commission, Washington, DC (USA). Office of Nuclear Regulatory Research; Harvard Univ., Boston, MA (USA). Harvard Air Cleaning Lab; 480 p; Feb 1991; p. 815-830; 21. Department of Energy/Nuclear Regulatory Commission (DOE/NRC) nuclear air cleaning conference; San Diego, CA (USA); 13-16 Aug 1990; CONF-900809--VOL.2; OSTI as TI91009673; NTIS; INIS; GPO
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Fortoul, T.I.; Valverde, M.; Lopez, M.C.; Avila-Costa, M.R.; Avila-Casado, M.C.; Mussali-Galante, P.; Gonzalez-Villalva, A.; Rojas, E.; Ostrosky-Shejet, P., E-mail: fortoul@servidor.unam.mx
arXiv e-print [ PDF ]2004
arXiv e-print [ PDF ]2004
AbstractAbstract
[en] We describe differences by sex in genotoxic damage found in a population of medical students exposed to a highly oxidative atmosphere, compared with a control group, measured by the single-cell gel electrophoresis assay and histological changes in nasal epithelium smears. Cells were obtained from the nasal epithelium and blood leukocytes. Higher DNA damage in nasal cells and leukocytes was found in males compared to females and control subjects. The percentage of squamous metaplastic changes in the nasal epithelium was also higher in males compared with females and controls. The commutation of normal nasal epithelium by squamous cells might modify its protective function in the nose, increasing the risk of damage to the lower respiratory tract. Although, as medical students, males and females were exposed to the same environment and activity patterns, male genotoxicity damage was higher in control and exposed subjects. More research should be done in order to identify direct or indirect sexual hormone intervention
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S0013935103000938; Copyright (c) 2003 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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[en] The environmental external gamma dose rate has been determined at the Mexican Nuclear Research Centre and surrounding communities, located in a forest area. Outdoor direct measurements of external gamma exposure and absorbed dose rates in air were performed using passive integrating thermoluminescent dosimeters. Radiological measurements were also carried out with a portable high pressure ionization chamber. The gamma dose rate was evaluated from data obtained along 10 years measurements. The activity concentrations of 40K, 226Ra, 232Th, 137Cs, and 235U in surface soil samples at sampling sites are also presented. The radionuclide activity concentrations were determined by low background gamma spectrometry with hyper-pure germanium detectors. A site specific lineal model to describe the relationship between the external gamma dose rate and the 226Ra concentration values in the soil is proposed. (author)
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30 refs.
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Journal of Radioanalytical and Nuclear Chemistry; ISSN 0236-5731; ; CODEN JRNCDM; v. 296(3); p. 1213-1218
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ACTINIDE NUCLEI, ALPHA DECAY RADIOISOTOPES, BETA DECAY RADIOISOTOPES, BETA-MINUS DECAY RADIOISOTOPES, BETA-PLUS DECAY RADIOISOTOPES, CESIUM ISOTOPES, DEVELOPING COUNTRIES, DOSIMETRY, ELECTRON CAPTURE RADIOISOTOPES, EVEN-EVEN NUCLEI, EVEN-ODD NUCLEI, GE SEMICONDUCTOR DETECTORS, HEAVY NUCLEI, INTERMEDIATE MASS NUCLEI, INTERNAL CONVERSION RADIOISOTOPES, ISOMERIC TRANSITION ISOTOPES, ISOTOPES, LATIN AMERICA, LIGHT NUCLEI, MEASURING INSTRUMENTS, MINUTES LIVING RADIOISOTOPES, NANOSECONDS LIVING RADIOISOTOPES, NORTH AMERICA, NUCLEI, ODD-EVEN NUCLEI, ODD-ODD NUCLEI, POTASSIUM ISOTOPES, RADIATION DETECTORS, RADIOISOTOPES, RADON ISOTOPES, SEMICONDUCTOR DETECTORS, SPECTROSCOPY, SPONTANEOUS FISSION RADIOISOTOPES, THORIUM ISOTOPES, URANIUM ISOTOPES, YEARS LIVING RADIOISOTOPES
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[en] In 1997-98, the Mediterranean Energy Observatory (l'Observatoire Mediterraneen de l'Energie, OME), within the framework of a working group composed of a number of specialists from Member companies, carried out a study on the prospects of the refining industry in the Mediterranean, looking forward to the year 2010. The declared objective of this work was to enlighten the various parties involved as to the consequences of decisions in the matter of refinery plant investment policy for the Mediterranean region, especially given the prospects of the progressive liberation of this sector. Based on analysis of the current situations and potential future situations developing from this, the study consisted of the projection of a range of scenarios, the characteristics and main results of which are presented below. (author)
Original Title
L'enjeu de l'industrie du raffinage en mediterranee
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Capote, G.; Perez, G.; Hernandez, A.T.; Pena, B.; LLanes, A.I.; Gongora, L.E.; Diaz, O.; Lopez, M.C.
V Anniversary. Scientific Event1993
V Anniversary. Scientific Event1993
AbstractAbstract
[en] The neutron activation analysis (NAA) is a highly accurate and sensitive non-destructive analytic technique. For this reason it is widely used for the multielemental determination of geological samples. In this work, 28 elements from 7 samples of source rocks are determined
Original Title
Analisis por activacion neutronica de muestras geologicas
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Secretaria Ejecutiva para Asuntos Nucleares, Holguin (Cuba). Delegacion Territorial; 36 p; 1993; p. 27; Secretaria Ejecutiva para Asuntos Nucleares; Holguin (Cuba)
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