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[en] A study of ³⁵k/³⁷k for the gas-phase elimination of hydrogen chloride from ethyl chloride is reported. The value found at 723K is 1.001 5+-0.000 2. Heavy atom kinetic isotope theory is applied in an attempt to characterise the transition state. It is concluded that there is only a moderate lengthening of the carbon-chlorine bond, and only a little motion of the chlorine atom in the transition state. (author)

Primary Subject

INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY (B1200)

Record Type

Journal Article

Journal

J. Chem. Soc. (London), Faraday Trans., I; v. 71(pt.10); p. 1937-1942

Country of publication

United Kingdom

Descriptors (DEI)

BOND LENGTHS, CHEMICAL BONDS, CHEMICAL REACTION KINETICS, CHLORINE 35, CHLORINE 37, DECOMPOSITION, ISOTOPE EFFECTS, MOLECULAR STRUCTURE, ORGANIC CHLORINE COMPOUNDS

Descriptors (DEC)

CHEMICAL REACTIONS, CHLORINE ISOTOPES, ISOTOPES, KINETICS, LIGHT NUCLEI, NUCLEI, ODD-EVEN NUCLEI, ORGANIC COMPOUNDS, ORGANIC HALOGEN COMPOUNDS, REACTION KINETICS, STABLE ISOTOPES

Reference NumberReference Number

7223199

INIS VolumeINIS Volume

INIS IssueINIS Issue

META

The use of on-site analysis for the protection of personnel

Loudon, A.G.; Koelbe-Boelke, J.; Adler, J.; Stach, J.1995

AbstractAbstract

[en] On-site analysis is the only way of providing protection for the personnel. In this paper some examples of such analyses using different instrument combinations are given. (authors). 5 figs., 1 tab

Primary Subject

RADIATION PROTECTION AND DOSIMETRY (F2300)

Record Type

Journal Article

Journal

Analusis; ISSN 0365-4877;

; CODEN ANLSCY; v. 23(2); p. M22-M24

Country of publication

France

Descriptors (DEI)

PERSONNEL, SAFETY ANALYSIS, SECURITY

LanguageLanguage

English

Reference NumberReference Number

27009169

INIS VolumeINIS Volume

INIS IssueINIS Issue

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