Filters
Results 1 - 1 of 1
Results 1 - 1 of 1.
Search took: 0.026 seconds
AbstractAbstract
[en] Cocrystallization experiments reported previously indicated a monovalent state existed for Md. Some of these experiments were repeated recently and a series of new ones was performed in which an attempt was made to prepare Md(I) by reduction with Sm2+ in an ethanolic or fused KCl medium. The oxidation state of Md was determined by the amount of 256Md tracer (>= 105 atoms) carried on precipitates of SmF2/SmF3, SmCl2, RbCl and Rb2PtCl6. Comparisons of the coprecipitation behavior of Md with the behavior of tracer amounts of the elements Es, Fm, Eu, Sr, Y and Cs showed that Md consistently follows the behavior of Fm2+, Eu2+ and Sr2+, rather than the behavior of Cs+. Therefore, it is concluded that Md cannot be reduced to a monovalent oxidation state with Sm2+ and that the earlier claim for Md(I) is unsubstantiated. (author)
Record Type
Journal Article
Journal
Journal of Inorganic and Nuclear Chemistry; ISSN 0022-1902; ; v. 41(12); p. 1743-1747
Country of publication
ACTINIDE COMPOUNDS, ACTINIDE NUCLEI, ALKALI METAL COMPOUNDS, ALKALINE EARTH METAL COMPOUNDS, BETA DECAY RADIOISOTOPES, CHEMICAL REACTIONS, CHLORIDES, CHLORINE COMPOUNDS, ELECTRON CAPTURE RADIOISOTOPES, FLUORIDES, FLUORINE COMPOUNDS, HALIDES, HALOGEN COMPOUNDS, HEAVY NUCLEI, HOURS LIVING RADIOISOTOPES, ISOTOPE APPLICATIONS, ISOTOPES, MENDELEVIUM ISOTOPES, NUCLEI, ODD-ODD NUCLEI, PLATINUM COMPOUNDS, PRECIPITATION, RADIOISOTOPES, RARE EARTH COMPOUNDS, RUBIDIUM COMPOUNDS, SAMARIUM COMPOUNDS, SEPARATION PROCESSES, TRANSITION ELEMENT COMPOUNDS, TRANSURANIUM COMPOUNDS
Reference NumberReference Number
INIS VolumeINIS Volume
INIS IssueINIS Issue