[en] The radiation copolymerization of allyl monomers with the diaminoethane was studied. The copolymerization reaction is used for the obtainment of mechanical precious materials on the base of unsaturated allyl monomers

[en] Full text: Expanding the practical use of products of radiation-vulcanized elastopolymers (RVEP) makes it necessary to increase their operational properties. Applied to the exploitation of polymers in the field of the ionizing radiation does not always meet shown requirements to them. In the present report the influence of sensitizer of disulpho chloride aromatic compounds on deformation-strength and their ageing under the influence of radiation exposure is being examined. The serial produced aromatic compounds of disulpho chloride bezene (DSCB) were used as sensitizers. It is established that, during the sensitization of radiation chemical vulcanization the mixture of butadiene-nitrile rubber with PVC with other ingredients affect the density of the spatial grid which determines the mechanical properties of vulcanized rubber. Two processes simultaneously run in the presence of sensitizing additives: inhibition of radiation oxidation which causes cross-linking and formation of the spatial grid in BNC. The role of sensitizer in the process of radiation vulcanization is defined first of all by reducing the doze of irradiation in the vulcanization process; simultaneously accelerate the cross-linking of the polymer chains. On the base of physical mechanical and structure of DSCB, can be judged that the influence of ionizing radiation leads the polar groups to ionization besides, their excited potential during ionization is very high which provides material with radiation resistance. Considering the resistance of DSCB to radiation, its practical value is high and can conduct vulcanization at low doses (150-300 kGy). (authors)

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