[en] Highlights: • SAFT-VR Mie produces highly accurate thermodynamic properties of ORC fluid systems. • Limiting superheating to a minimum leads to cycles with superior performance. • Generally, cycles with pure working fluids are more powerful and cost effective. • Large-glide fluid mixtures are attractive in applications with limited cooling resources. - Abstract: By employing the SAFT-VR Mie equation of state, molecular-based models are developed from which the thermodynamic properties of pure (i.e., single-component) organic fluids and their mixtures are calculated. This approach can enable the selection of optimal working fluids in organic Rankine cycle (ORC) applications, even in cases for which experimental data relating to mixture properties are not available. After developing models for perfluoroalkane (n-C_4F_1_0 + n-C_1_0F_2_2) mixtures, and validating these against available experimental data, SAFT-VR Mie is shown to predict accurately both the single-phase and saturation properties of these fluids. In particular, second-derivative properties (e.g., specific heat capacities), which are less reliably calculated by cubic equations of state (EoS), are accurately described using SAFT-VR Mie, thereby enabling an accurate prediction of important working-fluid properties such as the specific entropy. The property data are then used in thermodynamic cycle analyses for the evaluation of ORC performance and cost. The approach is applied to a specific case study in which a sub-critical, non-regenerative ORC system recovers and converts waste heat from a refinery flue-gas stream with fixed, predefined conditions. Results are compared with those obtained when employing analogue alkane mixtures (n-C_4H_1_0 + n-C_1_0H_2_2) for which sufficient thermodynamic property data exist. When unlimited quantities of cooling water are utilized, pure perfluorobutane (and pure butane) cycles exhibit higher power outputs and higher thermal efficiencies compared to mixtures with perfluorodecane (or decane), respectively. The effect of the composition of a working-fluid mixture in the aforementioned performance indicators is non-trivial. Only at low evaporator pressures (<10 bar) do the investigated mixtures perform better than the pure fluids. A basic cost analysis reveals that systems with pure perfluorobutane (and butane) fluids are associated with relatively high total costs, but are nevertheless more cost effective per unit power output than the fluid mixtures (due to the higher generated power). When the quantity of cooling water is constrained by the application, overall performance deteriorates, and mixtures emerge as the optimal working fluids.

[en] Highlights: • PV-T driven air-conditioning systems can cover 60% of the domestic heating demand. • PV-T air-conditioning systems can cover up to 100% of the domestic cooling needs. • The importance of high resolution energy performance simulations has been demonstrated. • The LCOE of PV-T air-conditioning varies between 0.06 and 0.12 €/kW h. - Abstract: Solar energy can play a leading role in reducing the current reliance on fossil fuels and in increasing renewable energy integration in the built environment, and its affordable deployment is widely recognised as an important global engineering grand challenge. Of particular interest are solar energy systems based on hybrid photovoltaic-thermal (PV-T) collectors, which can reach overall efficiencies of 70% or higher, with electrical efficiencies up to 15–20% and thermal efficiencies in excess of 50%, depending on the conditions. In most applications, the electrical output of a hybrid PV-T system is the priority, hence the contacting fluid is used to cool the PV cells and to maximise their electrical performance, which imposes a limit on the fluid’s downstream use. When optimising the overall output of PV-T systems for combined heating and/or cooling provision, this solution can cover more than 60% of the heating and about 50% of the cooling demands of households in the urban environment. To achieve this, PV-T systems can be coupled to heat pumps, or absorption refrigeration systems as viable alternatives to vapour-compression systems. This work considers the techno-economic challenges of such systems, when aiming at a low cost per kW h of combined energy generation (co- or tri-generation) in the housing sector. First, the technical viability and affordability of the proposed systems are studied in ten European locations, with local weather profiles, using annually and monthly averaged solar-irradiance and energy-demand data relating to homes with a total floor area of 100 m² (4–5 persons) and a rooftop area of 50 m². Based on annual simulations, Seville, Rome, Madrid and Bucharest emerge as the most promising locations from those examined, and the most efficient system configuration involves coupling PV-T panels to water-to-water heat pumps that use the PV-T thermal output to maximise the system’s COP. Hourly resolved transient models are then defined in TRNSYS, including thermal energy storage, in order to provide detailed estimates of system performance, since it is found that the temporal resolution (e.g. hourly, daily, yearly) of the simulations strongly affects their predicted performance. The TRNSYS results indicate that PV-T systems have the potential to cover 60% of the combined (space and hot water) heating and almost 100% of the cooling demands of homes (annually integrated) at all four aforementioned locations. Finally, when accounting for all useful energy outputs from the PV-T systems, the overall levelised cost of energy of these systems is found to be in the range of 0.06–0.12 €/kW h, which is 30–40% lower than that of equivalent PV-only systems.

[en] Although district heating networks have a key role to play in tackling greenhouse gas emissions associated with urban energy systems, little work has been carried out on district heating networks expansion in the literature. The present article develops a methodology to find the best district heating network expansion strategy under a set of given constraints. Using a mixed-integer linear programming approach, the model developed optimises the future energy centre operation by selecting the best mix of technologies to achieve a given purpose (e.g. cost savings maximisation or greenhouse gas emissions minimisation). Spatial expansion features are also considered in the methodology. Applied to a case study, the model demonstrates that depending on the optimisation performed, some building connection strategies have to be prioritised. Outputs also prove that district heating schemes' financial viability may be affected by the connection scenario chosen, highlighting the necessity of planning strategies for district heating networks. The proposed approach is highly flexible as it can be adapted to other district heating network schemes and modified to integrate more aspects and constraints. - Highlights: • A novel methodology evaluates the marginal expansion of district heating networks. • MILP optimisation model either maximizes profit or minimizes CO₂ emissions. • The model selects and operates the best mix of technologies to run the network. • The pipes layout is also optimised; model tested on a real case study. • Results show the influence of connection strategies on investment schedules.

[en] Highlights: • Thirty-one working fluids are investigated using a previously-validated NIFTE model. • Key fluid properties are the volume of vaporisation and maximum saturation pressure. • The maximum thermal efficiency of an ideal two-phase displacement cycle is 14–15%. • The maximum thermal and exergy efficiencies of the NIFTE are 1–2% and 6%. • R123, R142b, R245ca, butane, pentane, hexane are promising fluids depending on operating conditions. - Abstract: The Non-Inertive-Feedback Thermofluidic Engine (NIFTE) is a device capable of utilising low-grade heat to produce pumping work. An investigation on the applicability of different working fluids for the NIFTE is presented, with emphasis on the effects of key thermodynamic properties of the working fluid on: (i) the maximum thermal efficiency of an idealised two-phase positive-displacement cycle, and (ii) a prediction of the exergy efficiency of the NIFTE. The properties with the most dominant role in determining these efficiency measures were the change in specific volume due to vapourisation and the maximum saturation pressure in the cycle (linked to the pumping head during operation). Thirty-one pure working fluids were studied using a model of the NIFTE that features a dynamic heat exchanger description and a mechanism to account for thermal losses, presented in earlier work. For the scenario where the maximum cycle pressure was defined by the pumping application, higher efficiencies were predicted for wet and isentropic fluids. For the scenario where the hot and cold heat exchanger temperatures were set by the external heat source and sink, higher efficiencies were predicted for dry and isentropic fluids. The maximum pumping pressure and heat source temperature had non-monotonic effects on the efficiencies exhibited by different working fluids, which were linked to the role of molecular weight and polarity in determining the saturated vapour pressure during evaporation. For a particular NIFTE arrangement, setting and application, an optimum efficiency (and also pumping power output) was attained by selecting a working fluid with a particular maximum cycle (saturation) pressure; in the cases investigated here: 6% at 3.5 bar. Upper bound thermal efficiencies of 14–15% were predicted for the ‘best’ working fluid undergoing an ideal generalised two-phase positive-displacement cycle, whereas valve and thermal losses in the NIFTE allowed values no higher than 1–2%

[en] Highlights: • Optimal integrated selection and operation of distributed energy systems (DES). • Model informs stakeholders/decision-makers of technoeconomic investment trade-offs. • DES provide major security of supply and resource efficiency benefits. • CHP-based solutions offer better returns (28–30%) than PV-battery combination (13%). • CHP-ORC and CHP-absorption chiller solutions have paybacks within 3.5–3.7 years. Commercial buildings are large energy consumers and opportunities exist to improve the way they produce and consume electricity, heating and cooling. If energy system integration is feasible, this can lead to significant reductions in energy consumption and emissions. In this context, this work expands on an existing integrated Technology Selection and Operation (TSO) optimisation model for distributed energy systems (DES). The model considers combined heat and power (CHP) and organic Rankine cycle (ORC) engines, absorption chillers, photovoltaic panels and batteries with the aim of guiding decision makers in making attractive investments that are technically feasible and environmentally sound. A retrofit case study of a UK food distribution centre is presented to showcase the benefits and trade-offs that integrated energy systems present by contrasting outcomes when different technologies are considered. Results show that the preferred investment options select a CHP coupled either to an ORC unit or to an absorption chiller. These solutions provide appealing internal rates of return of 28–30% with paybacks within 3.5–3.7 years, while also decarbonising the building by 95–96% (if green gas is used to power the site). Overall, the TSO model provides valuable insights allowing stakeholders to make well-informed decisions when evaluating complex integrated energy systems.

[en] This paper is concerned with the emergence and development of low-to-medium-grade thermal-energy-conversion systems for distributed power generation based on thermodynamic vapor-phase heat-engine cycles undergone by organic working fluids, namely organic Rankine cycles (ORCs). ORC power systems are, to some extent, a relatively established and mature technology that is well-suited to converting low/medium-grade heat (at temperatures up to ~300–400°C) to useful work, at an output power scale from a few kilowatts to 10s of megawatts. Thermal efficiencies in excess of 25% are achievable at higher temperatures and larger scales, and efforts are currently in progress to improve the overall economic viability and thus uptake of ORC power systems, by focusing on advanced architectures, working-fluid selection, heat exchangers and expansion machines. Solar-power systems based on ORC technology have a significant potential to be used for distributed power generation, by converting thermal energy from simple and low-cost non-concentrated or low-concentration collectors to mechanical, hydraulic, or electrical energy. Current fields of use include mainly geothermal and biomass/biogas, as well as the recovery and conversion of waste heat, leading to improved energy efficiency, primary energy (i.e., fuel) use and emission minimization, yet the technology is highly transferable to solar-power generation as an affordable alternative to small-to-medium-scale photovoltaic systems. Solar-ORC systems offer naturally the advantages of providing a simultaneous thermal-energy output for hot water provision and/or space heating, and the particularly interesting possibility of relatively straightforward onsite (thermal) energy storage. Key performance characteristics are presented, and important heat transfer effects that act to limit performance are identified as noteworthy directions of future research for the further development of this technology.

[en] Highlights: • A modelling framework to compare different refrigeration systems is presented. • Water-cooled systems outperformed the air-cooled systems by 3% in the UK. • Water-cooled solutions can reduce energy use but have higher initial costs. • External temperature conditions impact the operation of a water-cooled condensers. • A hybrid approach maximises energy savings by 6% against air-cooled systems. -- Abstract: Refrigeration in supermarkets accounts between 30% and 60% of total electricity demand in UK stores. The aim of this study is to conduct a pre-feasibility analysis of whether the use of a water-cooled configuration rejecting heat to the soil can improve the overall cooling performance of commercial refrigeration systems against air-cooled designs. In this work, a model simulating the operation of an existing refrigeration system is presented and validated against field data measurements taken from a supermarket. The examined system is used as a baseline and then modified to evaluate the impact of installing a water-cooled gas cooler. Results indicate that the use of water-cooled gas coolers has the potential to reduce electrical consumption of refrigeration systems by up to a factor of 5 when external temperatures are high. Overall, annual operation indicates the water-cooled alternative uses 3% less electricity than the air-cooled approach. A hybrid system is also considered consisting of coupled air-cooled and water-cooled units operating in parallel, for which an energy reduction of 6% is obtained compared against the baseline system. An economic evaluation of these systems shows promising results with a payback period of about 5 years for systems installed in new stores, although retrofits are costlier.

[en] Highlights: • Semi-transparent solar cells are effective spectral-splitting optical filters. • Optical properties of solar cells significantly affect the solar energy allocation. • The proposed PVT collector can generate high-temperature (>100 °C) heat. • Perovskite solar cell is of great promise in next-generation PVT applications. • Detailed performance maps can assist designers in selecting the solar cell material. Spectral splitting is a promising design methodology that can significantly improve the performance of hybrid photovoltaic-thermal (PV-T) collectors. However, conventional spectral-splitting PVT (SSPVT) collectors require additional optical components, which significantly increases the complexity and cost of the collector. This study proposes SSPVT collector designs that employ semi-transparent photovoltaic (PV) solar cells, which act as both the electricity generator as well as the spectral-splitting optical filter. In these designs, a part of the solar spectrum is absorbed by the semi-transparent solar cells for electricity generation, while the rest (especially the near-infrared region of the solar spectrum) is transmitted to an absorber where it generates a high-temperature thermal energy output. Three types of emerging semi-transparent solar cells, i.e., cadmium telluride (CdTe), perovskite solar cells (PVSCs) and polymer solar cells (PSCs), are selected for investigation in this context. A comprehensive two-dimensional model of such SSPVT collectors is developed and used to investigate their electrical and thermal performance. The results show that the proposed designs are effective at thermally decoupling the PV cells from the solar thermal absorber, thereby promoting a higher electrical efficiency and enabling the simultaneous generation of low-temperature thermal energy (<60 °C), along with high-temperature thermal energy (100–200 °C) under one sun. For example, a PVSC-based SSPVT collector is shown to be capable of simultaneously generating: electricity with an efficiency of 13.8%, high-temperature heat (150 °C) with a thermal efficiency of 21.1%, and low-temperature heat (50 °C) with a thermal efficiency of 22.5%. The relative performance between the CdTe-, PVSC- and PSC-based collectors depend on the relative value of the high-temperature thermal energy to that of electricity. It is concluded that semi-transparent solar cells are of great promise in this application, and can give rise to next-generation, high-performance solar collectors.

[en] Highlights: • An ICE-ORC CHP system design tool is developed for optimising total power or fuel use. • Simultaneous optimisation of ICE-ORC CHP systems can increase total power output by 30%. • Optimal ICE exhaust gas temperature increases to promote ORC power generation by 7%. • Optimised ORCs generate up to 15% of the total power and reduce fuel consumption. • Power optimisation increases fuel consumption; fuel-efficiency optimisation reduces it by 17%. Organic Rankine cycle (ORC) engines are suitable for heat recovery from internal combustion engines (ICE) for the purpose of secondary power generation in combined heat and power (CHP) systems. However, trade-offs must be considered between ICE and ORC engine performance in such integrated solutions. The ICE design and operational characteristics influence its own performance, along with the exhaust-gas conditions available as heat source to the ORC engine, impacting ORC design and performance, while the heat-recovery heat exchanger (ORC evaporator) will affect the ICE operation. In this paper, an integrated ICE-ORC CHP whole-system optimisation framework is presented. This differs from other efforts in that we develop and apply a fully-integrated ICE-ORC CHP optimisation framework, considering the design and operation of both the ICE and ORC engines simultaneously within the combined system, to optimise the overall system performance. A dynamic ICE model is developed and validated, along with a steady-state model of subcritical recuperative ORC engines. Both naturally aspirated and turbocharged ICEs are considered, of two different sizes/capacities. Nine substances (covering low-GWP refrigerants and hydrocarbons) are investigated as potential ORC working fluids. The integrated ICE-ORC CHP system is optimised for either maximum total power output, or minimum fuel consumption. Results highlight that by optimising the complete integrated ICE-ORC CHP system simultaneously, the total power output increases by up to 30% in comparison to a nominal system design. In the integrated CHP system, the ICE power output is slightly lower than that obtained for optimal standalone ICE application, as the exhaust-gas temperature increases to promote the bottoming ORC engine performance, whose power increases by 7%. The ORC power output achieved accounts for up to 15% of the total power generated by the integrated system, increasing the system efficiency by up to 11%. When only power optimisation is performed, the specific fuel consumption increases, highlighting that high-power output comes at the cost of higher fuel consumption. In contrast, when specific fuel consumption is used as the objective function (minimised), fuel consumption drops by up to 17%, thereby significantly reducing the operating fuel costs. This study proves that by taking a holistic approach to whole-system ICE-ORC CHP design and operation optimisation, more power can be generated efficiently, with a lower fuel consumption. The findings are relevant to ICE and ORC manufacturers, integrators and installers, since it informs component design, system integration and operation decisions.

[en] Highlights: • Proposed off-design ORC optimisation tool considers component time-varying performance. • ORC power is underestimated by 17% if component off-design performance is excluded. • Optimised piston expander off-design isentropic efficiency increases by 10–16%. • Optimised off-design evaporator heat exchanger effectiveness improves by up to 15%. • Optimised off-design ORC performance maps are provided covering a wide operating range. -- Abstract: Organic Rankine cycle (ORC) engines often operate under variable heat-source conditions, so maximising performance at both nominal and off-design operation is crucial for the wider adoption of this technology. In this work, an off-design optimisation tool is developed and used to predict the impact of varying heat-source conditions on ORC operation. Unlike previous efforts where the performance of ORC engine components is assumed fixed, here we consider explicitly the time-varying operational characteristics of these components. A bottoming ORC system is first optimised for maximum power output when recovering heat from the exhaust gases of an internal-combustion engine (ICE) running at full load. A double-pipe heat exchanger (HEX) model is used for sizing the ORC evaporator and condenser, and a piston-expander model for sizing the expander. The ICE is then run at part-load, thus varying the temperature and mass flow rate of the exhaust gases. The tool predicts the new off-design heat transfer coefficients in the heat exchangers, and the new optimum expander operating points. Results reveal that the ORC engine power output is underestimated by up to 17% when the off-design operational characteristics of these components are not considered. In particular, the piston-expander isentropic efficiency increases at off-design operation by 10–16%, due to the reduced pressure ratio and flow rate in the system, while the evaporator effectiveness improves by up to 15%, due to the higher temperature difference across the HEX and a higher proportion of heat transfer taking place in the two-phase evaporating zone. As the ICE operates further away from its nominal point, the off-design ORC engine power output reduces by a lesser extent than that of the ICE. At an ICE part-load operation of 60% (by electrical power), the optimised ORC engine with fluids such as R1233zd operates at 77% of its nominal capacity. ORC off-design performance maps are generated, for characterising and predicting system performance, which can be used, along with the optimisation tool, by ORC system designers, manufacturers and plant operators to identify optimum performance under real operating conditions.