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McRaven, C.P.; Cich, M.J.; Lopez, G.V.; Sears, T.J.; Hurtmans, D.; Mantz, A.W.
Brookhaven National Laboratory (United States). Funding organisation: DOE - Office Of Science (United States)2011
Brookhaven National Laboratory (United States). Funding organisation: DOE - Office Of Science (United States)2011
AbstractAbstract
[en] We report measurements of self- and nitrogen-pressure broadening of the P(11) line in the ?1 + ?3 combination band of acetylene at 195 739.649 5135(80) GHz by absorption of radiation emitted by an extended cavity diode laser referenced to a femtosecond frequency comb. Broadening, shift and narrowing parameters were determined at 296 K. For the most appropriate, hard collision, model in units of cm-1/atm, we find 0.146317(27), 0.047271(104) and -0.0070819(22) for the acetylene self-broadening, narrowing and shift, and 0.081129(35), 0.022940(74) and -0.0088913(25) respectively, for the nitrogen-broadening parameters. The uncertainties are expressed as one standard deviation (in parenthesis) in units of the last digit reported. These parameters are 2-3 orders of magnitude more precise than those reported in previous measurements. Similar analyses of the experimental data using soft collision and simple Voigt lineshape models were made for comparison.
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Source
BNL--95220-2011-JA; KC0301020; AC02-98CH10886
Record Type
Journal Article
Journal
Journal of Molecular Spectroscopy; ISSN 0022-2852; ; v. 266(1); p. 43-51
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