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Rossijskaya Akademiya Nauk, Moscow (Russian Federation); Otdelenie Khimii i Nauk o Materialakh RAN, Moscow (Russian Federation); Ministerstvo Obrazovaniya i Nauki RF, Moscow (Russian Federation); Nauchnyj Sovet RAN po Neorganicheskoj Khimii, Moscow (Russian Federation); Rossijskij Fond Fundamental'nykh Issledovanij, Moscow (Russian Federation); Inst. Obshchej i Neorganicheskoj Khimii im. N.S. Kurnakova RAN, Moscow (Russian Federation); Inst. Khimii Rastvorov RAN, Ivanovo (Russian Federation); Ivanovskij Gosudarstvennyj Khimiko-Tekhnologicheskij Univ., Ivanovo (Russian Federation); Rossijskoe Khimicheskoe Obshchestvo im. D.I. Mendeleeva, Moscow (Russian Federation); 562 p; ISBN 978-5-85229-397-8; 
; 2011; p. 306-307; 25. International Chugaev conference on coordination chemistry; XXV Mezhdunarodnaya Chugaevskaya konferentsiya po koordinatsionnoj khimii i II Molodezhnaya konferentsiya-shkola Fiziko-khimicheskie metody v khimii koordinatsionnykh soedinenij; Suzdal (Russian Federation); 6-11 Jun 2011; 2. Youth conference-school Physicochemical methods in chemistry of coordination compounds; XXV Mezhdunarodnaya Chugaevskaya konferentsiya po koordinatsionnoj khimii i II Molodezhnaya konferentsiya-shkola Fiziko-khimicheskie metody v khimii koordinatsionnykh soedinenij; Suzdal (Russian Federation); 6-11 Jun 2011
; 2011; p. 306-307; 25. International Chugaev conference on coordination chemistry; XXV Mezhdunarodnaya Chugaevskaya konferentsiya po koordinatsionnoj khimii i II Molodezhnaya konferentsiya-shkola Fiziko-khimicheskie metody v khimii koordinatsionnykh soedinenij; Suzdal (Russian Federation); 6-11 Jun 2011; 2. Youth conference-school Physicochemical methods in chemistry of coordination compounds; XXV Mezhdunarodnaya Chugaevskaya konferentsiya po koordinatsionnoj khimii i II Molodezhnaya konferentsiya-shkola Fiziko-khimicheskie metody v khimii koordinatsionnykh soedinenij; Suzdal (Russian Federation); 6-11 Jun 2011
[en] Present article is devoted to technological aspects of synthesis of borohydrides of rare earth metals on the basis of model synthesis of metal hydrides. The diagram of obtaining of final output by means of auto initiation method has been drawn. The flowsheet of model synthesis of Ln(BH4)3 has been elaborated and proposed.
Journal
[en] The mechanism of synthesis of aluminum hydride, lithium aluminum hydride and borohydrides of lanthanides is considered. Synthesis of aluminum hydride, lithium aluminum hydride and borohydrides of lanthanides by auto initiation is modeled. (author)
Journal
Izvestiya Akademii Nauk Tadzhikskoj SSR. Otdelenie Fiziko-Matematicheskikh, Khimicheskikh i Geologicheskikh Nauk; ISSN 0002-3485; ; CODEN IATOAN; v. 3(144); p. 78-85
; CODEN IATOAN; v. 3(144); p. 78-85
[en] Present article is devoted to system analysis of enthalpy formation of gaseous lanthanide ions. The analysis of impact of various components for overall assessment of thermodynamic stability of complex compound is presented. The Born-Gabber cycle for determination of enthalpy formation of lanthanide borohydrides is made. By means of semiempirical method the complete data on formation enthalpy of gaseous ions of lanthanides is calculated. The change regularity of this value within lanthanides group if defined. (author)
Journal
[en] This article is devoted to energy properties of inorganic hydride compounds. The evaluation results of lanthanide borohydrides by means of Kapustinskiy's equation and Bon-Gabber cycle are considered. The thermochemical ion radius BH-4 is used at evaluations. The enthalpy of formation of lanthanide borohydrides is defined.
Journal
[en] The mechanism of process of synthesis of lanthanide borohydrides interaction of lanthanide chlorides with sodium borohydride was investigated. The formation of dual-lanthanide complex with sodium borohydride was considered. The oscillatory nature of synthesis and initiation role of the lanthanide borohydride was shown. Polynomial for programmed synthesis of lanthanide borohydrides was composed.
Journal