Kushida, K.; Ogawa, O.; Kuriyama, K.; Hayashi, N.; Ogura, M.; Hasegawa, M.; Kobayashi, N., E-mail: kuri@ionbeam.hosei.ac.jp2002
AbstractAbstract
[en] Substitution and electrical activation of carbon in 12C+- and 12C++31P+-implanted InP were studied for various annealing stages (773-923 K for 20 min). 12C+ was implanted into semi-insulating InP at a range of ∼3.0 μm with a total dose of 3x1014 cm-2. The co-implantation of 12C+ and 31P+ was performed at a range of ∼2.0 μm with an individual dose of 3x1014 cm-2. Rutherford back scattering, X-ray diffraction and Raman spectroscopy measurements showed the improvement of the crystallinity in the InP matrix by the annealing, indicating the disappearance of the introduced vacancy-interstitial pairs. Those were introduced during ion irradiation. All the annealed samples showed the n-type conduction by a van der Pauw method. The electric activation rate in the 12C+ implanted samples reached to 4.5% for those annealed at 923 K. For the co-implanted samples, the rate was slightly improved (∼7.3%). Nuclear reaction analyses for the 12C+-implanted samples using a 12C(d,p)13C reaction showed a tendency that carbon is easily incorporated into the interstitial lattice sites
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S0168583X01012320; Copyright (c) 2002 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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Nuclear Instruments and Methods in Physics Research. Section B, Beam Interactions with Materials and Atoms; ISSN 0168-583X; ; CODEN NIMBEU; v. 190(1-4); p. 869-872
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[en] This paper reports on activities of boron in the binary Ni-B and the ternary Co-Fe-B melts determined by the electromotive force (emf) measurement. A boron crystal was mainly used as the reference electrode, and a ternary 29 wt pct B2O3-42 wt pct CaO-29 wt pct Al2O3 oxide melt was used as the electrolyte. Large negative deviations from Raoult's law have been found in both the binary and the ternary systems. The activity of nickel has been calculated from the measured boron activity by means of the Gibbs-Duhem equation. Standard Gibbs energies of formation of Ni3B (s), Fe2B (s), and Co3B (s) were estimated and compared with available data
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