[en] In this paper we develop a technique for determining interatomic potentials in materials in the quantum regime from single-shell extended x-ray absorption spectroscopy (EXAFS) spectra. We introduce a pair distribution function, based on ordinary quantum time-independent perturbation theory. In the proposed scheme, the model potential parameters enter the distribution through a fourth-order Taylor expansion of the potential, and are directly refined in the fit of the model signal to the experimental spectrum. We discuss in general the validity of our theoretical framework, namely the quantum regime and perturbative treatment, and work out a simple tool for monitoring the sensitivity of our theory in determining lattice anharmonicities based on the statistical F-test. As an example, we apply our formalism to an EXAFS spectrum at the Ag K edge of AgI at T = 77 K. We determine the Ag-I potential parameters and find good agreement with previous studies

[en] A distributed electron cyclotron resonance plasma reactor powered by a microwave generator operating at 2.45 GHz was used to deposit a-C:H films at room temperature on RF biased (1 0 0) silicon substrates. Modifying the substrate bias, the ion dose rate and the composition of the precursor gas enabled the average deposited energy density to be varied. For the pure acetylene plasma and under constant substrate bias an increasing ion dose-rate leads to an increased sp³ hybridized C fraction. The effect is correlated to propagation and overlap of the hypersonic shock waves generated by high energy density collision cascades. The corresponding timescale is within the picosecond range. The shock wave related effects are enhanced when argon is added to the acetylene plasma. Once the collision cascades and shock wave comes to rest, the subsequent nucleation of the sp³ hybridized component is enhanced by the tensile stress-mediated nucleation process

[en] The surface topography of hydrogenated tetrahedral amorphous carbon (ta-C:H) is critical for various applications such as microelectromechanical devices, magnetic and optical storage devices, and medical implants. The surface topography of ta-C:H films deposited by distributed electron cyclotron resonance plasma from C₂H₂ gas precursor was investigated. The effects of pressure, together with ion flux and energy, are studied by atomic force microscopy in relation to the structural evolution of the films. The results are compared with the predictions of the Edward-Wilkinson model [Proc. R. Soc. London, Ser. A 44, 1039 (1966)] recently proposed to account for ta-C:H growth and with previous interpretations based on hypersonic shock waves. The random hillocks observed on the smooth surfaces of ta-C:H films deposited at high pressure are thought to result from the interference of high energy shock waves triggered by C₄H_x⁺ ions that produce overlapping collision cascades and induce nonlinear effects

[en] An intuitive description is given of a phenomenological model for the formation of Cooper pairs in cuprate superconductors. In this model, coupling is mediated by large lattice strains connected to anharmonic oscillations along c of the apical ions. A pair binding energy of the order of several hundred kelvin was obtained. (orig.)

[en] We study the measurement of the positions of atoms as a means of estimating the relative phase between two Bose-Einstein condensates. We consider N bosonic atoms released from a double-well trap, which form an interference pattern; we show that the measurement of the position of N atoms has a sensitivity that saturates the bound set by the quantum Fisher information, and allows for estimation at the Heisenberg limit of precision. Phase estimation through the measurement of the center of mass of the interference pattern can also provide sub-shot-noise sensitivity. Finally, we study the effect of an overlap of the two clouds on the estimation precision when Mach-Zehnder interferometry is performed in a double well. We find that a nonzero overlap of the clouds strongly reduces the phase sensitivity.

[en] We discuss the nature of symmetry breaking and the associated collective excitations for a system of bosons coupled to the electromagnetic field of two optical cavities. For the specific configuration realized in a recent experiment at ETH [1, 2], we show that, in absence of direct intercavity scattering and for parameters chosen such that the atoms couple symmetrically to both cavities, the system possesses an approximate U(1) symmetry which holds asymptotically for vanishing cavity field intensity. It corresponds to the invariance with respect to redistributing the total intensity $I=I_1+I_2$ between the two cavities. The spontaneous breaking of this symmetry gives rise to a broken continuous translation-invariance for the atoms, creating a supersolid-like order in the presence of a Bose–Einstein condensate. In particular, we show that atom-mediated scattering between the two cavities, which favors the state with equal light intensities $I_1=I_2$ and reduces the symmetry to ${\mathbf{Z}}_2\otimes <!--\; ???\; -->{\mathbf{Z}}_2$, gives rise to a finite value $\sim <!--\; ???\; -->\sqrt{I}$ of the effective Goldstone mass. For strong atom driving, this low energy mode is clearly separated from an effective Higgs excitation associated with changes of the total intensity I. In addition, we compute the spectral distribution of the cavity light field and show that both the Higgs and Goldstone mode acquire a finite lifetime due to Landau damping at non-zero temperature. (paper)

[en] The microstructure of distributed electron cyclotron resonance plasma-deposited hydrogenated amorphous carbon films (a-C:H) was investigated using electron diffraction, Raman spectroscopy, and Fourier transform infrared spectroscopy. Experimental evidence of the existence of transpolyacetylene (TPA) chains in a-C:H films free of nanocrystalline diamond is presented. The values of the mean bond angles and lengths and first neighbor numbers are consistent with the TPA data. The Raman spectra were fitted using the G and D bands and the bands centered at 1140, 1233, and 1475 cm-1 assigned to TPA chains modes. The relative intensity of the latter decreases while hydrogen content decreases. A significant sp²-CH olefinic mode contribution to the infrared stretching band is observed for the low-density films (∼1.2 g/cm3). TPA chains growth is enhanced when ion current density and energy decrease

[en] We study the instability of a superfluid flow through a constriction in three spatial dimensions. We consider a Bose-Einstein condensate at zero temperature in two different geometries: a straight waveguide and a torus. The constriction consists of a broad, repulsive penetrable barrier. In the hydrodynamic regime, we find that the flow becomes unstable as soon as the velocity at the classical (Thomas-Fermi) surface equals the sound speed inside the constriction. At this critical point, vortex rings enter the bulk region of the cloud. The nucleation and dynamics scenario is strongly affected by the presence of asymmetries in the velocity and density of the background condensate flow.

[en] We study the current-phase relation of a Bose-Einstein condensate flowing through a repulsive square barrier by solving analytically the one-dimensional Gross-Pitaevskii equation. The barrier height and width fix the current-phase relation j(δφ), which tends to j∼cos(δφ/2) for weak barriers and to the Josephson sinusoidal relation j∼sin(δφ) for strong barriers. Between these two limits, the current-phase relation depends on the barrier width. In particular, for wide-enough barriers, we observe two families of multivalued current-phase relations. Diagrams belonging to the first family, already known in the literature, can have two different positive values of the current at the same phase difference. The second family, new to our knowledge, can instead allow for three different positive currents still corresponding to the same phase difference. Finally, we show that the multivalued behavior arises from the competition between hydrodynamic and nonlinear-dispersive components of the flow, the latter due to the presence of a soliton inside the barrier region.

[en] The non-linear coupled particle light dynamics of an ultracold gas in the field of two independent counter-propagating laser beams can lead to the dynamical formation of a self-ordered lattice structure as presented in (2016) Phys. Rev. X 6 021026. Here we present new numerical studies on experimentally observable signatures to monitor the growth and properties of such a crystal in real time. While, at least theoretically, optimal non-destructive observation of the growth dynamics and the hallmarks of the crystalline phase can be performed by analyzing scattered light, monitoring the evolution of the particle’s momentum distribution via time-of-flight probing is an experimentally more accessible choice. In this work we show that both approaches allow us to unambiguously distinguish the crystal from independent collective scattering as it occurs in matter wave super-radiance. As a clear crystallization signature, we identify spatial locking between the two emerging standing laser waves, together creating the crystal potential. For sufficiently large systems, the system allows reversible adiabatic ramping into the crystalline phase as an alternative to a quench across the phase transition and growth from fluctuations. (paper)