[en] The development of new photocatalyst towards the highly efficient photo-reduction of U(VI) was highly desirable. In this study, ZIF-8/g-C₃N₄ photocatalyst was fabricated to photo-reduce U(VI) from aqueous solutions under different water chemistry. It is demonstrated that ZIF-8/g-C₃N₄ exhibited the fast-photocatalytic rate (completely photoreduction within 30 min), high photocatalytic activity (K_d > 10⁵ mL/g) and superior chemical stability (No significant decrease after fifth cycles). The photoreduction rate of U(VI) significantly decreased with increasing pH, H₂O₂ radicals and photo-generated electrons play an important role in U(VI) photoreduction by quenching experiments and ESR analysis. According to XPS and XANES analysis, adsorbed U(VI) was partly photo-reduced into U(IV) by ZIF-8/g-C₃N₄ photocatalyst. The highly efficient removal of U(VI) on ZIF-8/g-C₃N₄ photocatalyst was attributed to the synergistic effect of ZIF-8 and g-C₃N₄ photocatalyst. The present study may provide a new strategy to apply new photocatalyst for in-situ photoreduction of U(VI) in actual environmental remediation.

[en] Highlights: • The synthesis methods of MOF-derived carbons are reviewed. • The functions of monometal, bimetal, nonmetal and metal-free in MOF-derived carbons are summarized. • Recent catalytic applications of MOF-derived carbons are discussed. • The mechanisms of MOF-derived carbons are analyzed in catalysis. Carbon materials derived from metal organic frameworks (MOFs) have excellent properties of high surface area, high porosity, adjustable pore size, high conductivity and stability, and their applications in catalysis have become a rapidly expanding research field. In this review, we have summarized the synthesis strategies of MOF-derived carbons with different physical and chemical properties, obtained through direct carbonization, co-pyrolysis and post-treatment. The potential applications of derived carbons, especially monometal-, bimetal-, nonmetal-doped and metal-free carbons in organo-catalysis, photocatalysis and electrocatalysis are analyzed in detail from the environmental perspective. In addition, the improvement of catalytic efficiency is also considered from the aspects of increasing active sites, enhancing the activity of reactants and promoting free electron transfer. The function and synergy of various species of the composites in the catalytic reaction are summarized. The reaction paths and mechanisms are analyzed, and research ideas or trends are proposed for further development.

[en] Highlights: • The synthesis strategies of water-stable MOFs are briefly introduced. • The mechanisms mainly ascribe to coordination and electrostatic interaction. • Sufficient functional groups endow MOFs excellent performance. • Multi-factor influences demonstrate the practical application potential of MOFs. Because the pollutants produced by human activities have destroyed the ecological balance of natural water environment, and caused severe impact on human life safety and environmental security. Hence the task of water environment restoration is imminent. Metal-organic frameworks (MOFs), structured from organic ligands and inorganic metal ions, are notable for their outstanding crystallinity, diverse structures, large surface areas, adsorption performance, and excellent component tunability. The water stability of MOFs is a key requisite for their possible actual applications in separation, catalysis, adsorption, and other water environment remediation areas because it is necessary to safeguard the integrity of the material structure during utilization. In this article, we comprehensively review state-of-the-art research progress on the promising potential of MOFs as excellent nanomaterials to remove contaminants from the water environment. Firstly, the fundamental characteristics and preparation methods of several typical water-stable MOFs include UiO, MIL, and ZIF are introduced. Then, the removal property and mechanism of heavy metal ions, radionuclide contaminants, drugs, and organic dyes by different MOFs were compared. Finally, the application prospect of MOFs in pollutant remediation prospected. In this review, the synthesis methods and application in water pollutant removal are explored, which provide ways toward the effective use of water-stable MOFs in materials design and environmental remediation.