[en] Triarylantimony Ar₃Sb (Ar = 4-FC₆H₄, 3-MeC₆H₄) is oxidized by hydrogen peroxide to form tetranuclear complexes [(4-FC₆H₄)₂SbO]₄(O₂)₂ and [(3-MeC₆H₄)₂SbO]₄(O₂)₂ (as a DMSO solvate). The structure of the resulting compounds was examined by single crystal X-ray diffraction analysis.

[en] The differential inverse inelastic mean free paths (DIIMFP) of beryllium were derived from energy spectra acquired using X-ray photoelectron spectroscopy and electron energy loss spectroscopy techniques by means of the fitting of calculated spectra to experimental data. The calculation of the energy spectra is performed employing the partial intensity approach (PIA). The EELS and XPS spectra were acquired in different laboratories using different Be samples. The comparison of the obtained DIIMFPs with literature data is presented. (paper)

[en] The relative concentration of deuterium implanted into a beryllium sample is determined by elastic peak electron spectroscopy (EPES). The method of partial intensities based on solution of the boundary value problem for the transport equation by the invariant embedding method is used for subsequent determination of the energy spectra of reflected electrons. The differential inverse inelastic mean free paths (DIIMFPs) and the differential surface excitation probability (DSEP) are retrieved using a fitting procedure based on numerous solutions of the direct problem with fitting parameters. The high efficiency of the fitting procedure is based on the technique of numerical solution of equations for the partial intensities, which combines precision and a record-high calculation speed. In the work DIIMFP and DSEP are obtained for both the surface region and for a homogeneous array in the bulk. Calculations of DIIMFP and DSEP are carried out for pure beryllium and for beryllium samples implanted with deuterium. The relative concentrations of deuterium into beryllium were determined at a different fluence. The obtained values of the relative deuterium concentrations are n_D/n_Be = 0.12 ± 0.02 and 0.15 ± 0.03 for an irradiation dose of 5.5 × 10²¹ and 20.1 × 10²¹ m^–2, respectively. The results indicate that, in comparison with the methods used earlier, the developed method allows an order of magnitude in of the sensitivity of determining the relative hydrogen-isotope concentration in compounds to be attained.

[en] We are publishing recent results in chalcogenide photoelectric convertors fabrication, which are efforts of many scientific teams from Russia, Belarus, Ukraine, and Kazakhstan. Competitively high efficiency of photoelectric convertors (11.4% for CdTe and 11% for CIGS) was achieved in the process of our work. Furthermore, luminescent filters for improvement of spectral response of such chalcogenide solar cells in a short wavelengths region were also developed and investigated here.