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[en] KNb3O8 showed blue luminescence of 450 nm at 300 K. The emission spectra of K4Nb6O17 and KNb3O8 at 77 K were red-shifted by H2O intercalation and H+-exchange, indicating that the photochemical properties of these hosts were changed with interlayer conditions. (author)
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[en] The excitation and emission spectra of CaWO4, MgWO4, PbWO4, ZnWO4, and CaMoO4 were analyzed by a configurational coordination model. The spectral line shapes simulated by a configurational coordination model with a singlet ground state and an excited triplet state well explained the line shape of the luminescence spectra and the line shape at the rising part of the excitation spectra of these salts at room temperature. The energy level of the excited triplet state and the reorganization energies at the ground state and the triplet state were determined. It was concluded that the potential curve at the excited state becomes shallower than that at the ground state for these systems. (author)
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[en] Highly crystallized luminescent SrWO4 film has been prepared on a tungsten substrate in an alkaline solution containing strontium ions by an electrochemical method using constant direct current of 1 mA/cm2 at room temperature (25 C). This film showed only a single blue emission at 461 nm with the excitation of 248 nm at liquid nitrogen temperature (-196 C), strongly suggesting it consists of well-crystallized defect-free crystals
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Numerical Data
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ALKALINE EARTH METAL COMPOUNDS, AMPLIFIERS, CHALCOGENIDES, COHERENT SCATTERING, CRYSTAL STRUCTURE, CURRENTS, DATA, DIFFRACTION, ELECTRON MICROSCOPY, EMISSION, EQUIPMENT, FILMS, INFORMATION, LASER SPECTROSCOPY, LASERS, MICROSCOPY, NUMERICAL DATA, OXIDES, OXYGEN COMPOUNDS, PHOTON EMISSION, SCATTERING, SPECTROSCOPY, STRONTIUM COMPOUNDS, TRANSITION ELEMENT COMPOUNDS, TUNGSTEN COMPOUNDS
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[en] Electrochemical luminescence (ECL) at n-type ZnO semiconductor electrode was measured under anodic polarization. Scanning the potential imposed on the ZnO electrode, emission was suddenly observed around +20 V. Using the ZnO electrodes doped with rare earth metal ions as Sm3+, Eu3+, Dy3+, Ho3+ and Er3+, much brighter emission was obtained than the ECL of non-doped ZnO. These emission spectra are ascribed to the rare earth metal ions, respectively. This result would show that emission centers of doped ions were selectively excited by electrons that were injected from electrolyte to the electrode by avalanche breakdown under strong anodic bias on the ZnO
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S0169-4332(06)00260-1; Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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