[en] The photoluminescence of the CdS nanoclusters formed in the matrix of a Langmuir-Blodgett film is studied in the temperature range 5-300 K. At the temperature 5 K, the photoluminescence spectrum of the nanocrystals consists of two bands, with peaks at 2.95 and 2.30 eV. The temperature dependence of the position of the high-energy photoluminescence band differs from the temperature dependence of the band gap of the CdS bulk crystal. The integrated photoluminescence intensity of this band decreases as temperature increases in the range from 5 to 75 K, increases in the range from 150 to 230 K, and decreases above 230 K. The experimental data are interpreted in the context of the model of recombination of nonequilibrium charge carriers in CdS nanoclusters with regard to the charge-carrier transport in locally coupled clusters different in size. In the model, the energy depth of the traps for electrons is estimated at 120 meV; the estimations of the activation energies of nonradiative recombination yield 5 and 100 meV

[en] The optical properties of CdS nanoclusters are studied for samples in which the nanoclusters are embedded in the Langmuir-Blodgett film matrix or the matrix is removed by annealing in vacuum or ammonia atmosphere. After annealing the samples in vacuum or ammonia, the bands of emission from the nanoclusters and from the surface states appear in the photoluminescence spectrum, with the peaks at 2.9 or 2.7 eV and at 1.9 or 2.1 eV, respectively. It is found that, after treating the samples with ammonia, the photoluminescence of the nanoclusters becomes more intense, whereas the photoluminescence corresponding to recombination via the levels of the surface states becomes less intense. It is established that the increase in the photoluminescence intensity for the nanoclusters and the difference between the temperature dependence of the photoluminescence peak position and the temperature dependence of the band gap of bulk CdS are due to passivation of surface states in the nanoclusters. The experimental data are interpreted in the model of recombination of nonequilibrium charge carriers in the CdS nanoclusters, taking into account the exchange of charge carriers between the nanocrystals and trapping centers at their surface and the recombination of charge carriers via the levels of the surface states.

[en] The enhancement of Raman scattering by optical phonon modes in quantum dots was achieved in resonant and surface-enhanced Raman scattering experiments by approaching the laser energy to the energy of either the interband transitions or the localized surface plasmons in silver nanoclusters deposited onto the nanostructures. Resonant Raman scattering by TO, LO, and SO phonons as well as their overtones was observed for PbS, ZnS, and ZnO quantum dots while enhancement for LO and SO modes in CdS quantum dots with a factor of about 700 was measured in surface enhanced Raman scattering experiments. Multiple phonon Raman scattering observed up to 5th and 7th order for CdS and ZnO, respectively, confirms the high crystalline quality of the grown QDs.

No abstract available

[en] Raman scattering (including nonresonant, resonant, and surface enhanced scattering) of light by optical and surface phonons of ZnO nanocrystals and nanorods has been investigated. It has been found that the nonresonant and resonant Raman scattering spectra of the nanostructures exhibit typical vibrational modes, E₂(high) and A₁(LO), respectively, which are allowed by the selection rules. The deposition of silver nanoclusters on the surface of nanostructures leads either to an abrupt increase in the intensity (by a factor of 10³) of Raman scattering of light by surface optical phonons or to the appearance of new surface modes, which indicates the observation of the phenomenon of surface enhanced Raman light scattering. It has been demonstrated that the frequencies of surface optical phonon modes of the studied nanostructures are in good agreement with the theoretical values obtained from calculations performed within the effective dielectric function model.